CBSE Class 12 Chemistry Question Paper 2026 (Set 2 - 56/3/2) with Solutions is now available here for download. CBSE conducted the Class 12 Chemistry examination on February 28, 2026, from 10:30 AM to 1:30 PM.

CBSE Class 12 Chemistry paper is of total 100 marks out of which 70 marks are allocated to the theory paper and 30 marks are for practical examination.

The theory paper consists of 33 questions divided into five sections:

  • Section A contains Multiple Choice Questions (MCQs),
  • Section B contains Very Short Answer Type (VSA) Questions,
  • Section C contains Short Answer Type (SA) Questions,
  • Section D contains Case-Study based Questions,
  • Section E contains Long Answer (LA) Type Questions.

All sections are compulsory.

CBSE Class 12 Chemistry Question Paper 2026 (Set 2 - 56/3/2) with Solution PDF

CBSE Class 12 Chemistry 2026 Set 2 (56/3/2) Questions with Solutions

Question 1:

The mole fraction of a solute in 2.0 molal aqueous solution is :

  • (A) 1.87
  • (B) 0.347
  • (C) 0.0347
  • (D) 0.00347

Question 2:

On electrolysis of very dilute aqueous solution of NaCl using platinum electrodes :

  • (A) H\(_2\) gas is evolved at anode.
  • (B) Na is produced at cathode.
  • (C) O\(_2\) gas is evolved at anode.
  • (D) H\(_2\) gas is evolved at cathode.

Question 3:

Which of the following compounds is most reactive towards nucleophilic substitution reaction with aqueous NaOH ?

  • (A) Figure A
  • (B) Figure B
  • (C) Figure C
  • (D) Figure D

Question 4:

The dehydration of 1\(^\circ\), 2\(^\circ\) and 3\(^\circ\) alcohols follows the order :

  • (A) 2\(^\circ\) > 1\(^\circ\) > 3\(^\circ\)
  • (B) 3\(^\circ\) > 2\(^\circ\) > 1\(^\circ\)
  • (C) 1\(^\circ\) > 2\(^\circ\) > 3\(^\circ\)
  • (D) 1\(^\circ\) > 3\(^\circ\) > 2\(^\circ\)

Question 5:

The oxidation number of Co in [Co(NH\(_3\))\(_5\)(ONO)]SO\(_4\) is :

  • (A) +3
  • (B) +2
  • (C) +4
  • (D) +6

Question 6:

According to Werner's theory, the primary valencies of the central metal atom :

  • (A) are satisfied by neutral molecules or negative ions.
  • (B) are equal to its coordination number.
  • (C) are satisfied by negative ions.
  • (D) are non-ionisable.

Question 7:

Which reagent is used to distinguish between C\(_2\)H\(_5\)NH\(_2\) and (C\(_2\)H\(_5\))\(_2\)NH ?

  • (A) KMnO\(_4\)
  • (B) CHCl\(_3\) + KOH (ethanolic)
  • (C) NaOH + I\(_2\)
  • (D) Neutral FeCl\(_3\)

Question 8:

Among the following, which one has the lowest value of pK\(_b\) ?

  • (A) Figure A
  • (B) Figure B
  • (C) Figure C
  • (D) Figure D

Question 9:

In aqueous acidified solution, CrO\(_4^{2-}\) ion converts to which of the following ?

  • (A) CrO\(_3\)
  • (B) Cr\(^{3+}\)
  • (C) Cr\(_2\)O\(_7^{2-}\)
  • (D) CrO

Question 10:

The boiling point of an azeotropic mixture of water and nitric acid is more than that of pure water and nitric acid. The mixture shows :

  • (A) no deviation from Raoult's law
  • (B) that solution is an ideal solution
  • (C) positive deviation from Raoult's law
  • (D) negative deviation from Raoult's law

Question 11:

On hydrolysis, which of the following carbohydrates gives only glucose ?

  • (A) Starch
  • (B) Sucrose
  • (C) Lactose
  • (D) Galactose

Question 12:

For the reaction \(2A \rightarrow 3B\), the rate of reaction \(\frac{d[B]}{dt}\) is equal to :

  • (A) \(-\frac{3}{2}\frac{d[A]}{dt}\)
  • (B) \(-\frac{2}{3}\frac{d[A]}{dt}\)
  • (C) \(-\frac{1}{2}\frac{d[A]}{dt}\)
  • (D) \(\frac{3\,d[A]}{dt}\)

Question 13:

Assertion (A) : Separation of Zr and Hf is difficult. Reason (R) : Zr and Hf have almost identical atomic and ionic radii due to lanthanoid contraction.

  • (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • (B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • (C) Assertion (A) is true, but Reason (R) is false.
  • (D) Assertion (A) is false, but Reason (R) is true.

Question 14:

Assertion (A): Phenol is less acidic than 4-methylphenol. Reason (R): The presence of an electron releasing group in phenol makes it less acidic.

  • (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A).
  • (B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of Assertion (A).
  • (C) Assertion (A) is true, but Reason (R) is false.
  • (D) Assertion (A) is false, but Reason (R) is true.

Question 15:

Assertion (A) : Aromatic primary amines can easily be prepared by Gabriel phthalimide synthesis. Reason (R) : Gabriel phthalimide synthesis is used to prepare only aliphatic primary amines.

  • (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • (B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • (C) Assertion (A) is true, but Reason (R) is false.
  • (D) Assertion (A) is false, but Reason (R) is true.

Question 16:

Assertion (A) : Order of reaction is not applicable for elementary reaction but applicable for complex reaction. Reason (R) : Order of reaction is an experimental quantity.

  • (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • (B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • (C) Assertion (A) is true, but Reason (R) is false.
  • (D) Assertion (A) is false, but Reason (R) is true.

Question 17:

Explain why, on addition of 1 mol of KCl to 1 litre of water, the boiling point of water increases, while the addition of 1 mol of methyl alcohol to 1 litre of water decreases the boiling point.


Question 18:

Write IUPAC names of the following compounds :
(i) \( \mathrm{[PtCl_2(en)_2]SO_4} \)
(ii) \( \mathrm{(NH_4)_2[CoF_4]} \)


Question 19:

Define the following terms with a suitable example in each case :
(i) Ambidentate ligand
(ii) Double salt


Question 20:

For the compound having molecular formula C\(_4\)H\(_9\)Br, write : (a) the isomer which is most reactive towards SN1 displacement. (b) the isomer which, on reacting with Na metal in the presence of dry ether, gives 2,5-Dimethylhexane.


Question 21:

For a reaction A + B → Products, the rate law is \(\mathrm{Rate = k[A][B]^{3/2}}\). Write the overall order of the reaction. Can this reaction be an elementary reaction ? Give reason in support of your answer.


Question 22:

How do you explain the following ? (a) Presence of a carbonyl group in glucose (b) Presence of five --OH groups in glucose


Question 23:

Give reasons for the following : (a) Alkyl halides, though polar, yet their solubility in water is very low.


Question 24:

Give reasons for the following : (b) p-Dichlorobenzene has higher melting point than those of o- and m-isomers.


Question 25:

Give reasons for the following : (c) CH\(_3\)--I is more reactive than CH\(_3\)--Br towards SN2 reactions.


Question 26:

How will you obtain the following from benzene diazonium chloride ? Write chemical equations involved : (a) Phenol


Question 27:

How will you obtain the following from benzene diazonium chloride ? Write chemical equations involved : (b) Iodobenzene


Question 28:

How will you obtain the following from benzene diazonium chloride ? Write chemical equations involved : (c) p-Aminoazobenzene


Question 29:

An organic compound (A) with molecular formula C\(_3\)H\(_5\)N on reaction with C\(_6\)H\(_5\)MgBr followed by hydrolysis, gives a compound (B). Compound (B) forms an orange-red precipitate with 2,4-DNP reagent and does not give iodoform test. It neither reduces Tollens' or Fehling's reagent nor does it decolourise bromine water. On drastic oxidation with chromic acid it gives a carboxylic acid (C) having molecular formula C\(_7\)H\(_6\)O\(_2\). Identify the compounds (A), (B) and (C). Write the reactions of compound (A) with C\(_6\)H\(_5\)MgBr followed by hydrolysis to give compound (B).


Question 30:

An antifreeze solution is prepared by dissolving 31 g of ethylene glycol (Molar mass = 62 g mol\(^{-1}\)) in 600 g of water. Calculate the freezing point of the solution. (K\(_f\) for water = 1.86 K kg mol\(^{-1}\))


Question 31:

Answer the following questions about the complexes \(\mathrm{[NiCl_4]^{2-}}\) and \(\mathrm{[Ni(CN)_4]^{2-}}\) :
(i) Write the hybridization involved in each case.
(ii) Which of them is the inner orbital complex and which one is the outer orbital complex ?
(iii) Compare their magnetic behaviour. [Atomic number : Ni = 28]


Question 32:

(i) Name two coordination compounds which are important in biological systems. (ii) What is meant by chelate effect ? Give an example. (iii) Why are low spin tetrahedral complexes rarely formed ?


Question 33:

State Kohlrausch's law of independent migration of ions. With the help of a curve, explain why it is not easy to determine \(\Lambda_m^\circ\) for weak electrolytes by extrapolating the concentration--molar conductivity curve, as it is for strong electrolytes.


Question 34:

The half-life period of a radioactive element is \(\mathrm{1.5\times10^{10}}\) years. Calculate the time in which the activity of the element is reduced to 75% of its original value. [Given : log 2 = 0·30, log 3 = 0·48, log 4 = 0·60]


Question 35:

Name the reagents used in the following reactions : (i) Oxidation of a primary alcohol to aldehyde (ii) Oxidation of a primary alcohol to carboxylic acid


Question 36:

Write the reaction involved in Kolbe's reaction.


Question 37:

Why are tertiary alcohols resistant to oxidation ?


Question 38:

Write the products of the following reaction : \[ (CH_3)_3C-O-C_2H_5 \xrightarrow{HI} ? \]


Question 39:

Living systems are made up of various complex biomolecules like carbohydrates, proteins, nucleic acids, lipids, etc. Proteins and carbohydrates are essential constituents of our food. In addition, some simple molecules like vitamins and mineral salts also play an important role in the functions of organisms. All proteins are polymers of \(\mathrm{\alpha}\)-amino acids. Proteins can be classified into two types on the basis of their molecular shape — Fibrous and Globular proteins. Vitamins are accessory food factors required in the diet. They are classified as fat-soluble and water-soluble. Deficiency of vitamins leads to many diseases. Nucleic acids are the polymers of nucleotides which in turn consist of a base, a pentose sugar and phosphate moiety. There are two types of nucleic acids — DNA and RNA. Nucleic acids are responsible for the transfer of characters from parents to offsprings.


Question 40:

Write the name of basic building units of proteins and nucleic acids. How can you differentiate between Fibrous and Globular proteins on the basis of their structures ?


Question 41:

What products would be formed when a nucleotide from DNA containing thymine is hydrolyzed ?


Question 42:

Write one structural difference between DNA and RNA.


Question 43:

Give one example each of a fat-soluble vitamin and a water-soluble vitamin.


Question 44:

Answer the following: \[ (a)(i)\;\text{Calculate the electrode potential of a half-cell for zinc electrode dipping in }0.01M\;ZnSO_4\text{ solution at }25^\circ C. \] \[ E^\circ_{Zn^{2+}/Zn}=-0.76V,\quad \log 10=1 \] \[ (a)(ii)\;\text{Write anode, cathode and overall reaction involved in dry cell.} \] \[ (a)(iii)\;\text{Equilibrium constant }(K_c)\text{ is related to }E^\circ_{\text{cell}},\text{ but not to }E_{\text{cell}}.\text{ Why?} \]


Question 45:

(b) (i) The conductivity of 0.001 M solution of acetic acid is \( 3.905 \times 10^{-5}\ \mathrm{S\ cm^{-1}} \). Calculate its molar conductivity and degree of dissociation (\( \alpha \)).

Given : \( \lambda^\circ_{\mathrm{CH_3COO^-}} = 40.9\ \mathrm{S\ cm^2\ mol^{-1}} \)

\( \lambda^\circ_{\mathrm{H^+}} = 349.6\ \mathrm{S\ cm^2\ mol^{-1}} \)

(ii) Give reasons for the following :

(I) Why does a mercury cell deliver a constant voltage for its entire life ?

(II) Why is it necessary to use salt bridge in a galvanic cell ?


Question 46:

Answer the following: \[ (a)(i)\;\text{Describe giving reason which one of the following pairs has the property indicated:} \] \[ (I)\;Fe\text{ or }Cu-\text{higher melting point} \] \[ (II)\;Ti^{3+}\text{ or }Sc^{3+}-\text{coloured in aqueous solution} \] \[ (III)\;Cr\text{ or }Zn-\text{higher third ionisation enthalpy} \] \[ (a)(ii)\;\text{Write the ionic equations for the oxidizing action of }MnO_4^-\text{ in acidic medium with:} \] \[ (I)\;Fe^{2+}\text{ ion} \] \[ (II)\;I^-\text{ ion} \]


Question 47:

A black-brown coloured solid (A) when fused with KOH in the presence of air, produces a dark green coloured compound (B) which on electrolytic oxidation in alkaline medium gives a dark purple coloured compound (C). Identify (A), (B) and (C). Write the reactions involved.


Question 48:

\[ \text{What happens when an acidic solution of the green compound }(B)\text{ is allowed to stand for some time? Also write the equation involved. What is this type of reaction called?} \]


Question 49:

Answer the following: \[ (a)(i)\;\text{Write the product(s) when:} \] \[ (I)\;\text{One mol of ethanal is treated with }1\text{ mol of }CH_3OH\text{ in the presence of dry }HCl\text{ gas.} \] \[ (II)\;\text{Benzaldehyde is treated with conc. }NaOH. \] \[ (III)\;\text{Ethanoic acid is heated in the presence of }P_2O_5. \] \[ (a)(ii)\;\text{Write a simple chemical test to distinguish between ethanal and propanal.} \] \[ (a)(iii)\;\text{Write the name of the reagent to transform allyl alcohol to propenal.} \]


Question 50:

Write the product(s) when : (I) One mol of ethanal is treated with 1 mol of \(CH_3OH\) in the presence of dry HCl gas. (II) Benzaldehyde is treated with conc. NaOH. (III) Ethanoic acid is heated in the presence of \(P_2O_5\).


Question 51:

(i) Draw the structure of the semicarbazone of acetone.

(ii) Why are \( \alpha \)-hydrogen atoms of aldehydes and ketones acidic in nature ?

(iii) Arrange the following compounds in increasing order of their reactivity towards HCN :

\( \mathrm{CH_3COCH_3,\ CH_3CHO,\ (CH_3)_3C-CO-CH_3} \)

(iv) Write the reaction involved in Etard reaction.

(v) Write the product when \( \mathrm{C_6H_{11}-CHO} \) reacts with Zn(Hg)/conc. HCl.



CBSE Class 12 Chemistry Paper Structure

Question Type Description
Very Short Answer 1–2 line answers, definitions, or simple equations
Short Answer Explanations, derivations, or numerical problems
Long Answer Detailed answers, reaction mechanisms, or calculations
Case-based / Integrated Questions based on a given situation may include calculations or reasoning

CBSE Class 12 Chemistry | Paper Analysis