Question:

Which one of the following is not present in the nitration mixture?

Updated On: Apr 4, 2024
  • $\overset{+}NO_2$
  • $HSO_4^{-}$
  • $SO^{2-}_4$
  • $H_2O$
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The Correct Option is C

Solution and Explanation

Nitration mixture contains equimolar ratio (i.e. $1: 1)$ of nitric acid and sulphuric acid. It contains $\underset{+}{N}O _{2}, HSO _{4}^{-}$ and $H _{2} O$ species. It does not contain $SO _{4}^{2-}$ ions. This can be explained on the basis of generation of nitronium $\overset{+}{N}O _{2}$ ion from nitrating mixture. Generation of $\overset{+}{N}O _{2}$ ion Step 1
Step II $H - \overset{\underset{|}{H}}{O^+} - NO_2 {<=>} \overset{+}{N}O_2 + H_2O$
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Concepts Used:

Group 15 Elements

Group 15 elements are also known as nitrogen group elements or nitrogen family

It consists of:

  • Nitrogen (N)
  • Phosphorus (P)
  • Arsenic (As)
  • Antimony (Sb)
  • Bismuth (Bi)
  • Moscovium (Mc)

They are present on the right side of the periodic table. All the elements are arranged based on their atomic weight. The elements with similar properties reside in a column called the group.

All Group 15 elements have the electron configuration ns2np3 in their outer shell, where n is the principal quantum number.

Periodic Trends in Group 15 Elements