List of top Chemistry Questions

Match List-I with List-II :

List - I(Test/reagent)	List - II(Radical identified)
(A) Lake Test	(I) NO3−
(B) Nessler’s Reagent	(II) Fe3+
(C) Potassium sulphocyanide	(III) Al3+
(D) Brown Ring Test	(IV) NH4+

Identify the correct answer from the options given below :

A first row transition metal with the highest enthalpy of atomisation, upon reaction with oxygen at high temperature, forms oxides of formula \( \text{M}_2\text{O}_n \) (where \( n = 3, 4, 5 \)). The 'spin-only' magnetic moment value of the amphoteric oxide from the above oxides is ___ BM (near integer).
(Given atomic number: \( \text{Sc: 21, Ti: 22, V: 23, Cr: 24, Mn: 25, Fe: 26, Co: 27, Ni: 28, Cu: 29, Zn: 30} \))

Given below are the two statements: one is labelled as Assertion (A) and the other is labeled as Reason (R).
Assertion (A): There is a considerable increase in covalent radius from N to P. However from As to Bi only a small increase in covalent radius is observed.
Reason (R): covalent and ionic radii in a particular oxidation state increases down the group.
In the light of the above statement, choose the most appropriate answer from the options given below:

Number of amine compounds from the following giving solids which are soluble in NaOH upon reaction with Hinsberg's reagent is _____.

If IUPAC name of an element is “Unununnium” then the element belongs to nth group of periodic table. The value of n is______

The molecular formula of second homologue in the homologous series of monocarboxylic acid is

Choose the correct statements from the following:
A Ethane-1,2-diamine is a chelating ligand.
B Metallic aluminium is produced by electrolysis of aluminium oxide in presence of cryolite.
C Cyanide ion is used as a ligand for leaching of silver.
D Phosphine acts as a ligand in Wilkinson catalyst.
E The stability constants of \( \text{Ca}^{2+} \) and \( \text{Mg}^{2+} \) are similar to EDTA complexes.

A closed vessel contains 10 g of an ideal gas X at 300 K, which exerts 2 atm pressure. At the same temperature, 80 g of another ideal gas Y is added to it and the pressure becomes 6 atm. The ratio of root mean square velocities of X and Y at 300 K is

For a sparingly soluble salt \( \text{AB}_2 \), the equilibrium concentrations of \( \text{A}^{2+} \) ions and \( \text{B}^- \) ions are \( 1.2 \times 10^{-4} \, \text{M} \) and \( 0.24 \times 10^{-3} \, \text{M} \), respectively. The solubility product of \( \text{AB}_2 \) is:

Given below are two statements: Statement I: $\text{PF}_5$ and $\text{BrF}_5$ both exhibit $\text{sp}^3\text{d}$ hybridisation.Statement II: Both $\text{SF}_6$ and $[\text{Co}(\text{NH}_3)_6]^{3+}$ exhibit $\text{sp}^3\text{d}^2$ hybridisation. In the light of the above statements,choose the correct answer from the options given below:

Given below are two statements :
Statement I : The higher oxidation states are more stable down the group among transition elements unlike p-block elements.
Statement II : Copper can not liberate hydrogen from weak acids.
In the light of the above statements, choose the correct answer from the options given below

Which of the following compound can give positive iodoform test when treated with aqueous KOH solution followed by potassium hypoiodite.

When '$x \times 10^{-2} \, \text{mL}$' methanol (molar mass $= 32 \, \text{g}$; density $= 0.792 \, \text{g/cm}^3$) is added to $100 \, \text{mL}$ water (density $= 1 \, \text{g/cm}^3$), the following diagram is obtained.

x = __________ (nearest integer)  
[Given: Molal freezing point depression constant of water at $273.15 \, \text{K}$ is $1.86 \, \text{K kg mol}^{-1}$]

For the electrochemical cell
M|M$^{2+}$||X$^{2-}$|X
If $E^0_{(M^{2+}/M)} = 0.46$ V and $E^0_{(X/X^{2-})} = 0.34$ V.
Which of the following is correct?

A molecule X associates in a given solvent as per the following equation:
X ⇌ (X)_n
For a given concentration of X, the van’t Hoff factor was found to be 0.80 and the
fraction of associated molecules was 0.3. The correct value of ‘n’ is:

If an iron (III) complex with the formula \[\left[ \text{Fe}(\text{NH}_3)_x (\text{CN})_y \right]^-\]has no electron in its \( e_g \) orbital, then the value of \( x + y \) is:

The final product A, formed in the following reaction sequence is:

According to IUPAC system, the compound

The major product C in the below mentioned reaction is:

Total number of stereo isomers possible for the given structure:

\([ \text{Mn}_2(\text{CO})_{10} ]\) and \([ \text{Co}_2(\text{CO})_8 ]\) structures have:A. Metal-Metal linkage
B. Terminal CO groups
C. Bridging CO groups
D. Metal in zero oxidation stateChoose the correct answer from the options given below:

Mass of glucose (\(C_6H_{12}O_6\)) required to be dissolved to prepare one litre of its solution which is isotonic with \(15 \, \text{g L}^{-1}\) solution of urea (\(NH_2CONH_2\)) is:
{Given:} Molar mass in \(\text{g mol}^{-1}\): \[ C : 12, \, H : 1, \, O : 16, \, N : 14 \]

Rate constants of a reaction at 500 K and 700 K are \(0.04 \, \text{s}^{-1}\) and \(0.14 \, \text{s}^{-1}\), respectively. Then, the activation energy of the reaction is:
{Given:} \[ \log 3.5 = 0.5441, \, R = 8.31 \, \text{J K}^{-1} \, \text{mol}^{-1} \]

The alkane that can be oxidized to the corresponding alcohol by KMnO₄ as per the equation

is, when: