The calomel electrode is commonly used as a reference electrode in electrochemical measurements. It consists of mercury (\( \text{Hg} \)) in contact with mercurous chloride (calomel, \( \text{Hg}_2\text{Cl}_2 \)) in a saturated potassium chloride (\( \text{KCl} \)) solution.
The calomel electrode falls under the category of "Metal – Insoluble Salt – Anion electrodes" because it involves a metal (\( \text{Hg} \)), an insoluble salt (\( \text{Hg}_2\text{Cl}_2 \)), and the chloride ions (\( \text{Cl}^- \)) in solution.
The correct answer is Option (1): Metal – Insoluble Salt – Anion electrodes.