The process with negative entropy change is :
- Dissolution of iodine in water
- Synthesis of ammonia from $N_2$ and $H_2$
- Dissolution of ${CaSO4(s) }$ to ${CaO(s)}$ and ${SO3(g)}$
- Subimation of dry ice
The Correct Option is B
Solution and Explanation
Top Questions on Spontaneity
- For independent processes at 300K
Process ΔH/kJmol−1 ΔS/JK−1 A -25 -80 B -22 40 C 25 -50 D 22 20
The number of non-spontaneous processes from the following is- JEE Main - 2023
- Chemistry
- Spontaneity
- Match List I with List IIChoose the correct answer from the options given below:
List I List II A Physisorption i Single Layer Adsorption B Chemisorption ii 20−40kJmol−1 C N2(g)+3H2(g)—⇢Fe(s)—⇢2NH3(g) iii Chromatography D Analytical Application or Adsorption iv Heterogeneous catalysis - JEE Main - 2023
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Given are two statements one is labelled as Assertion A and other is labelled as Reason R.
Assertion A : Magnesium can reduce Al2O3 at a temperature below 1350°C, while above 1350°C aluminium can reduce MgO.
Reason R : The melting and boiling points of magnesium are lower than those of aluminium.
In light of the above statements, choose the most appropriate answer from the options given below :- JEE Main - 2022
- Chemistry
- Spontaneity
- When the same quantity of heat is absorbed by a system at two different temperatures $T_1$ and $T_2$, such that $T_1 > T_2$, change in entropies are $\Delta S_1$ and $\Delta S_2$ respectively. Then
- KCET - 2020
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The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume of 10 liters to 20 liters at 25° is
- VITEEE - 2019
- Chemistry
- Spontaneity
Questions Asked in JEE Main exam
- Let \[\vec{a} = \hat{i} + \hat{j} + \hat{k}, \quad \vec{b} = -\hat{i} - 8\hat{j} + 2\hat{k}, \quad \text{and} \quad \vec{c} = 4\hat{i} + c_2\hat{j} + c_3\hat{k} \]be three vectors such that \[\vec{b} \times \vec{a} = \vec{c} \times \vec{a}.\]If the angle between the vector $\vec{c}$ and the vector $3\hat{i} + 4\hat{j} + \hat{k}$ is $\theta$, then the greatest integer less than or equal to $\tan^2 \theta$ is:
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- 10 mL of gaseous hydrocarbon on combustion gives 40 mL of CO\(_2\)(g) and 50 mL of water vapour. The total number of carbon and hydrogen atoms in the hydrocarbon is ______ .
- JEE Main - 2024
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- If each term of a geometric progression \( a_1, a_2, a_3, \dots \) with \( a_1 = \frac{1}{8} \) and \( a_2 \neq a_1 \), is the arithmetic mean of the next two terms and \( S_n = a_1 + a_2 + \dots + a_n \), then \( S_{20} - S_{18} \) is equal to
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A body of mass 1000 kg is moving horizontally with a velocity of 6 m/s. If 200 kg extra mass is added, the final velocity (in m/s) is:
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- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- p -Block Elements
Concepts Used:
Spontaneity
Spontaneity comes under the First Law of Thermodynamics that is based on the law of conservation of energy which explains that energy can be transformed from one form to another but cannot be created or destroyed. The spontaneity in thermodynamics defines the direction of heat flow that can be developed by establishing a relationship between the work done by the system or by the system. All of the processes of heat flow which happen naturally tend to proceed spontaneously only in one direction.
Spontaneous Reaction
A spontaneous chemical reaction is an irreversible process where you can’t get the ingredients back without the external agents.
Total entropy change is the essential parameter that defines the spontaneity of any process. Since most of the chemical reactions fall under the category of a closed system and open system; we can say there is a change in enthalpy too along with the change in entropy. Since, change in enthalpy also increases or decreases the randomness by affecting the molecular motions, entropy change alone cannot account for the spontaneity of such a process. Therefore, for explaining the spontaneity of a process we use the Gibbs energy change. Gibbs’ energy is a state function and an extensive property. The general expression for Gibbs energy change at constant temperature is expressed as:
ΔGsys = ΔHsys – TΔSsys
Here,
Change in Gibbs energy of the system = ΔGsys
Change in enthalpy of the system = ΔHsys
Change in Entropy of the system = ΔSsys
Constant Temperature of the system = T
Also, if we conduct a spontaneous process, the total change in entropy is always greater than zero.
Mathematical expression for the above spontaneous reaction meaning expression is
ΔSsys + ΔSsurr = ΔStotal
Here,
ΔStotal = total change in entropy for the process
ΔSsurr = change in entropy of the surrounding
ΔSsys = change in entropy of the system
Also, for a spontaneous process, the total change in entropy is 0, i.e. ΔStotal> 0.
Therefore;
TΔSsys – ΔHsys>0
ΔHsys– TΔSsys<0
Using the Gibbs equation, it can be said that
ΔGsys< 0
Thus, it can be inferred that any process is spontaneous if the change in Gibbs energy of the system is less than zero or else the process is not spontaneous.
This by the already provided equations the spontaneity can be predicted.
- During an exothermic reaction, the system has a negative enthalpy which inturn makes all the exothermic reactions spontaneous.
- During an endothermic reaction when the temperature or the entropy change is extremely high then the Gibbs free energy becomes negative.
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