Match List I with List IIList I List II A Physisorption i Single Layer Adsorption B Chemisorption ii 20−40kJmol−1 C N2(g)+3H2(g)—⇢Fe(s)—⇢2NH3(g) iii Chromatography D Analytical Application or Adsorption iv Heterogeneous catalysis
Choose the correct answer from the options given below:
| List I | List II | ||
| A | Physisorption | i | Single Layer Adsorption |
| B | Chemisorption | ii | 20−40kJmol−1 |
| C | N2(g)+3H2(g)—⇢Fe(s)—⇢2NH3(g) | iii | Chromatography |
| D | Analytical Application or Adsorption | iv | Heterogeneous catalysis |
- A - III, B - IV, C - I, D - II
- A - II, B - III, C - I, D - IV
- A - II, B - I, C - IV, D - III
- A - IV, B - II, C - III, D - I
The Correct Option is C
Solution and Explanation
(B) Physisorption is multi-layered and chemisorption is unimolecular layered.
(C) In heterogeneous catalysis, medium and catalyst are in different phases.
(D) Chromatography uses adsorption to purify/separate mixtures
So , the correct option is (C) : A - II, B - I, C - IV, D - III
Top Questions on Spontaneity
- For independent processes at 300K
Process ΔH/kJmol−1 ΔS/JK−1 A -25 -80 B -22 40 C 25 -50 D 22 20
The number of non-spontaneous processes from the following is- JEE Main - 2023
- Chemistry
- Spontaneity
Given are two statements one is labelled as Assertion A and other is labelled as Reason R.
Assertion A : Magnesium can reduce Al2O3 at a temperature below 1350°C, while above 1350°C aluminium can reduce MgO.
Reason R : The melting and boiling points of magnesium are lower than those of aluminium.
In light of the above statements, choose the most appropriate answer from the options given below :- JEE Main - 2022
- Chemistry
- Spontaneity
- When the same quantity of heat is absorbed by a system at two different temperatures $T_1$ and $T_2$, such that $T_1 > T_2$, change in entropies are $\Delta S_1$ and $\Delta S_2$ respectively. Then
- KCET - 2020
- Chemistry
- Spontaneity
- The process with negative entropy change is :
- JEE Main - 2019
- Chemistry
- Spontaneity
The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume of 10 liters to 20 liters at 25° is
- VITEEE - 2019
- Chemistry
- Spontaneity
Questions Asked in JEE Main exam
- Let \[\vec{a} = \hat{i} + \hat{j} + \hat{k}, \quad \vec{b} = -\hat{i} - 8\hat{j} + 2\hat{k}, \quad \text{and} \quad \vec{c} = 4\hat{i} + c_2\hat{j} + c_3\hat{k} \]be three vectors such that \[\vec{b} \times \vec{a} = \vec{c} \times \vec{a}.\]If the angle between the vector $\vec{c}$ and the vector $3\hat{i} + 4\hat{j} + \hat{k}$ is $\theta$, then the greatest integer less than or equal to $\tan^2 \theta$ is:
- JEE Main - 2024
- Vector Algebra
- 10 mL of gaseous hydrocarbon on combustion gives 40 mL of CO\(_2\)(g) and 50 mL of water vapour. The total number of carbon and hydrogen atoms in the hydrocarbon is ______ .
- JEE Main - 2024
- Hydrocarbons
- If each term of a geometric progression \( a_1, a_2, a_3, \dots \) with \( a_1 = \frac{1}{8} \) and \( a_2 \neq a_1 \), is the arithmetic mean of the next two terms and \( S_n = a_1 + a_2 + \dots + a_n \), then \( S_{20} - S_{18} \) is equal to
- JEE Main - 2024
- Arithmetic Mean
A body of mass 1000 kg is moving horizontally with a velocity of 6 m/s. If 200 kg extra mass is added, the final velocity (in m/s) is:
- JEE Main - 2024
- speed and velocity
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- p -Block Elements
Concepts Used:
Thermodynamics
Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.
Important Terms
System
A thermodynamic system is a specific portion of matter with a definite boundary on which our attention is focused. The system boundary may be real or imaginary, fixed or deformable.
There are three types of systems:
- Isolated System – An isolated system cannot exchange both energy and mass with its surroundings. The universe is considered an isolated system.
- Closed System – Across the boundary of the closed system, the transfer of energy takes place but the transfer of mass doesn’t take place. Refrigerators and compression of gas in the piston-cylinder assembly are examples of closed systems.
- Open System – In an open system, the mass and energy both may be transferred between the system and surroundings. A steam turbine is an example of an open system.
Thermodynamic Process
A system undergoes a thermodynamic process when there is some energetic change within the system that is associated with changes in pressure, volume and internal energy.
There are four types of thermodynamic process that have their unique properties, and they are:
- Adiabatic Process – A process in which no heat transfer takes place.
- Isochoric Process – A thermodynamic process taking place at constant volume is known as the isochoric process.
- Isobaric Process – A process in which no change in pressure occurs.
- Isothermal Process – A process in which no change in temperature occurs.
Laws of Thermodynamics
Zeroth Law of Thermodynamics
The Zeroth law of thermodynamics states that if two bodies are individually in equilibrium with a separate third body, then the first two bodies are also in thermal equilibrium with each other.
First Law of Thermodynamics
The First law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.
Second Law of Thermodynamics
The Second law of thermodynamics is a physical law of thermodynamics about heat and loss in its conversion.
Third Law of Thermodynamics
Third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: The entropy of a system approaches a constant value when its temperature approaches absolute zero.
SUBSCRIBE TO OUR NEWS LETTER
