Question:
What is the ratio of σ and pi bonds in pyrophosphoric acid ?
What is the ratio of σ and pi bonds in pyrophosphoric acid ?
Show Hint
In polyatomic structures, count sigma and pi bonds systematically by identifying single and double bonds.
Updated On: Mar 28, 2026
Show Solution
Verified By Collegedunia
Solution and Explanation
The structure of pyrophosphoric acid (H4P2O7) consists of an O=P-O-P=O backbone with terminal hydroxyl groups (OH).
Step 1: Counting Sigma (\( \sigma \)) Bonds:
- Each single bond (P-O and O-H) is a sigma bond.
- Each double bond (P=O) contains 1 sigma bond.
Total sigma bonds: 12 (8 single P-O and O-H bonds + 4 sigma components from P=O bonds).
Step 2: Counting Pi (\( \pi \)) Bonds:
- Each double bond (P=O) contains 1 pi bond.
Total pi bonds: 2 (from P=O bonds).
Step 3: Ratio of Sigma to Pi Bonds:
\[ \frac{\sigma}{\pi} = \frac{12}{2} = 6 \]
Conclusion:
The ratio of sigma to pi bonds in pyrophosphoric acid is 6:1.
Was this answer helpful?
1
0
Top JEE Main Chemistry Questions
- $A +2 B +3 C \rightleftharpoons AB _{2} C _{3}$ Reaction of $6.0\, g$ of $A , 6.0 \times 10^{23}$ atoms of $B$, and $0.036\, mol$ of $C$ yields $4.8\, g$ of compound $AB _{2} C _{3}$. If the atomic mass of $A$ and $C$ are 60 and 80 amu respectively, the atomic mass of $B$ is (Avogadro no. $=6 \times 10^{23}$ ):
- JEE Main - 2015
- Chemistry
- Some basic concepts of chemistry
- A water sample has ppm level concentration of following anions $F^{-} = 10 ;\, SO^{2-}_4 = 100 ;\, NO^{-}_3 = 50$ The anion/anions that make/makes the water sample unsuitable for drinking is / are :
- JEE Main - 2017
- Chemistry
- Environmental Chemistry
- Among the following oxoacids, the correct decreasing order of acidic strength is
- JEE Main - 2014
- Chemistry
- p -Block Elements
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)- Consider the reversible isothermal expansion of an ideal gas in a closed system at two different temperatures $T_1$ and $T_2 (T_1 < T_2)$. The correct graphical depiction of the dependence of work done $(w)$ on the final volume $(V)$ is:
- JEE Main - 2019
- Chemistry
- Thermodynamics
View More Questions
Top JEE Main p -Block Elements Questions
- Among the following oxoacids, the correct decreasing order of acidic strength is
- JEE Main - 2014
- Chemistry
- p -Block Elements
- $\textbf{Reduction potential of ions are given below:}$
\[ \begin{array}{ccc} \text{ClO}_4^- & \text{IO}_4^- & \text{BrO}_4^- \\ E^\circ = 1.19 \, \text{V} & E^\circ = 1.65 \, \text{V} & E^\circ = 1.74 \, \text{V} \\ \end{array} \]
The correct order of their oxidising power is:- JEE Main - 2024
- Chemistry
- p -Block Elements
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- Chemistry
- p -Block Elements
The number of oxygen atoms present in chemical formula of fuming sulphuric acid is _______.
- JEE Main - 2024
- Chemistry
- p -Block Elements
- Identify the correct statements about p-block elements and their compounds.
(A) Non metals have higher electronegativity than metals.
(B) Non metals have lower ionisation enthalpy than metals.
(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or neutral in nature.- JEE Main - 2024
- Chemistry
- p -Block Elements
View More Questions
Top JEE Main Questions
- For a positive integer $n$, if the mean of the binomial coefficients in the expansion of $(a + b)^{2n - 3}$ is 16, then $n$ is equal to :
- JEE Main - 2018
- binomial expansion formula
- Figure shows a network of capacitors where the numbers indicates capacitances in micro Farad. The value of capacitance $C$ if the equivalent capacitance between point $A$ and $B$ is to be $1\, \mu F$ is :
- JEE Main - 2016
- electrostatic potential and capacitance
- Given the masses of various atomic particles $m _{ p }=1.0072 u$ , $m _{ n }=1.0087 \,u$ $m _{ e }=0.000548 u$ , $m _{\overline{ v }}=0$, $m _{ d }=2.0141 u$ where $p \equiv$ proton, $n \equiv$ neutron, $e \equiv$ electron, $\overline{ v } \equiv$ antineutrino and $d \equiv$ deuteron. Which of the following process is allowed by momentum and energy conservation ?
- Find the binding energy per nucleon for ${ }_{50}^{120} Sn$. Mass of proton $m _{ p }=1.00783\, U ,$ mass of neutron $m_{n}=1.00867 \,U$ and mass of tin nucleus $m _{ Sn }=119.902199 \,U $ (take $1U = 931 \,MeV)$
- The locus of a point which divides the line segment joining the point (0, -1) and a point on the parabola, $x^2 = 4y$, internally in the ratio 1 : 2, is :
- JEE Main - 2020
- Conic sections
View More Questions
Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family