Question:

The most reactive to nucleophilic attack at the carbonyl group is

Updated On: Jun 14, 2022
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The Correct Option is B

Solution and Explanation

The case with which a nucleophile attacks the carbonyl group depends upon the electron deficiency, i.e. the magnitude of positive charge on carbonyl group carbon. Since, among all the groups attached

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has maximum electron withdrawing effect, electron deficiency will be maximum at carbonyl carbon of acetyl chloride. Hence, acetyl chloride, i.e.


is most reactive to nucleophilic attack at carbonyl group
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Concepts Used:

Hydrocarbons - Reaction Mechanism

Hydrocarbons are organic compounds that are entirely made up of only two kinds of atoms – carbon and hydrogen. Typically, hydrocarbons are colourless gases that have very weak odours.

Mechanism of electrophilic substitution reactions:

According to experimental evidences, SE (S = substitution; E = electrophilic) reactions are supposed to proceed via the following three steps:

  1. Generation of the electrophile
  2. Formation of carbocation intermediate
  3. Removal of proton from the carbocation interm