
The question involves two isobaric processes for the same mass of an ideal gas as depicted in the graph, where the x-axis represents temperature (\( T \)) and the y-axis represents volume (\( V \)). In isobaric processes, the pressure is constant, but the temperature and volume can change.
From the given graph, the lines \( P_1 \) and \( P_2 \) represent two different isobaric conditions, starting from the origin \( O \). The slope of each line in a \( V-T \) diagram represents the relationship between \( V \) and \( T \) under constant pressure. The steeper the slope, the lower the pressure.
Thus, the correct relationship is \( P_1 > P_2 \), making option \( P_1 > P_2 \) the correct answer.
From the ideal gas law:
\[ PV = nRT \]
Rearranging for volume:
\[ V = \left( \frac{nR}{P} \right) T \]
The slope of the line in the \( V-T \) graph for an isobaric process is proportional to \( \frac{1}{P} \). Therefore, we have:
\[ \text{Slope} \propto \frac{1}{P} \]
Comparing slopes:\[ (\text{Slope})_2 > (\text{Slope})_1 \quad \implies \quad P_2 < P_1 \]
A sample of n-octane (1.14 g) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is 5 kJ K\(^{-1}\). As a result of combustion, the temperature of the calorimeter increased by 5 K. The magnitude of the heat of combustion at constant volume is ___
A perfect gas (0.1 mol) having \( \bar{C}_V = 1.50 \) R (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is ____ J (nearest integer) [Given : R = 0.082 L atm K\(^{-1}\)] 
Given below are two statements:
Statement (I):
 
 are isomeric compounds. 
Statement (II): 
 are functional group isomers.
In the light of the above statements, choose the correct answer from the options given below:
The effect of temperature on the spontaneity of reactions are represented as: Which of the following is correct?
