Concept:
Different regions of the electromagnetic spectrum possess different wavelengths, frequencies and energies. Hence, each region has specific practical applications.
Step 1: Identify the application of microwaves
Microwaves are strongly absorbed by water molecules.
Therefore they are used in
\[
\boxed{\text{Heating and warming food}}
\]
Hence,
\[
P \rightarrow II
\]
Step 2: Identify the application of ultraviolet rays
Ultraviolet radiation possesses sufficient energy to destroy microorganisms.
Therefore UV rays are used for
\[
\boxed{\text{Purifying water}}
\]
Hence,
\[
Q \rightarrow I
\]
Step 3: Identify the application of gamma rays
Gamma rays have extremely high frequency and energy.
They are used in radiotherapy for destroying cancerous cells.
Therefore,
\[
R \rightarrow IV
\]
Step 4: Identify the application of radio waves
Radio waves are used in communication systems.
AM and FM broadcasting operate using radio waves.
Hence,
\[
S \rightarrow III
\]
Step 5: Write the final matching
\[
P-II,\quad Q-I,\quad R-IV,\quad S-III
\]
Therefore,
\[
\boxed{\text{Option (D)}}
\]