Boiling points are influenced by molecular weight, polarity, and hydrogen bonding: - n-Butane is non-polar and has the lowest boiling point. - Ethoxyethane has weak dipole-dipole interactions. - Pentanal has stronger dipole-dipole interactions. - Pentan-1-ol has hydrogen bonding, resulting in the highest boiling point. The correct order is n-Butane < Ethoxyethane < Pentanal < Pentan-1-ol.