Select Goal &
City
Select Goal
Explore
Question:
The correct option(s) regarding the complex ${[Co(en)(NH3)3(H2O)]^{3+} (en = H2NCH2CH2NH2)}$ is (are)
The correct option(s) regarding the complex ${[Co(en)(NH3)3(H2O)]^{3+} (en = H2NCH2CH2NH2)}$ is (are)
Updated On: Jun 14, 2022
- It has two geometrical isomers
- It will have three geometrical isomers if bidentate ?en? is replaced by two cyanide ligands
- It is paramagnetic
- It absorbs light at longer wavelength as compared to ${[Co(en)(NH3)4]^{3+}}$
Hide Solution
Verified By Collegedunia
The Correct Option is D
Solution and Explanation
(A) ${[Co(en)(NH_3)_3 (H_2O)]^{+3}}$ complex is type of ${[M(AA)b_3 c ]} $ have two G.I.
(B) If (en) is replaced by two cynide ligand, complex will be type of ${ [Ma3b2c]}$ and have 3 G.I.
(C) ${[Co(en)(NH3)3(H2O)]^{3+}}$ have d6 configuration ${(t^6_{2g})}$ on central metal with SFL therefore it is dimagnetic
in nature.
(D) Complex ${ [Co(en)(NH3)3(H2O)]^{3+}}$ have lesser ${CFSE (\Delta_O)}$ value than ${[Co(en)(NH3)4]^{3+}}$ therefore complex ${ [Co(en)(NH3)3(H2O)]^{+}}$ absorbs longer wavelength for d-d transition.
(B) If (en) is replaced by two cynide ligand, complex will be type of ${ [Ma3b2c]}$ and have 3 G.I.
(C) ${[Co(en)(NH3)3(H2O)]^{3+}}$ have d6 configuration ${(t^6_{2g})}$ on central metal with SFL therefore it is dimagnetic
in nature.
(D) Complex ${ [Co(en)(NH3)3(H2O)]^{3+}}$ have lesser ${CFSE (\Delta_O)}$ value than ${[Co(en)(NH3)4]^{3+}}$ therefore complex ${ [Co(en)(NH3)3(H2O)]^{+}}$ absorbs longer wavelength for d-d transition.
Was this answer helpful?
0
0
Top Questions on coordination compounds
- Find the total number of sigma and pi bonds in 2-formyl hex-4-enoic acid.
- JEE Main - 2024
- Chemistry
- coordination compounds
- Which of the following set contains both diamagnetic ions?
- JEE Main - 2024
- Chemistry
- coordination compounds
- The maximum coordination number of $Sn^{4+} is _____.
- GATE ES - 2024
- Environmental Chemistry
- coordination compounds
- Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.
[en = H2NCH2CH2NH2]- JEE Advanced - 2024
- Chemistry
- coordination compounds
- Among the following complexes, the total number of diamagnetic species is ______.
[Mn(NH3)6]3+, [MnCl6]3−, [FeF6]3−, [CoF6]3−, [Fe(NH3)6]3+, and [Co(en)3]3+
[Given, atomic number: Mn = 25, Fe = 26, Co = 27;
en = H2NCH2CH2NH2]- JEE Advanced - 2024
- Chemistry
- coordination compounds
View More Questions
Questions Asked in JEE Advanced exam
- Let \(S=\left\{\begin{pmatrix} 0 & 1 & c \\ 1 & a & d\\ 1 & b & e \end{pmatrix}:a,b,c,d,e\in\left\{0,1\right\}\ \text{and} |A|\in \left\{-1,1\right\}\right\}\), where |A| denotes the determinant of A. Then the number of elements in S is _______.
- JEE Advanced - 2024
- Matrices
- A block of mass \(5 kg\) moves along the \(x-\)direction subject to the force \(F = (−20x + 10) N,\) with the value of \(x \) in metre. At time \(t = 0 s,\) it is at rest at position \(x = 1 m\). The position and momentum of the block at \(t = (\pi/4)\) s are
- JEE Advanced - 2024
- Work-energy theorem
- Two equilateral-triangular prisms \(P_1 \)and \(P_2\) are kept with their sides parallel to each other, in vacuum, as shown in the figure. A light ray enters prism \(P_1\) at an angle of incidence 𝜃 such that the outgoing ray undergoes minimum deviation in prism \(P_2\). If the respective refractive indices of \(P_1\) and\( P_2\) are \(√ 3 /2\) and \(√3\), then \(\theta = sin{−1}[\sqrt \frac{ 3}{ 2} sin ( \frac{\pi}{B} )],\) where the value of \(\beta\) is ______.
- JEE Advanced - 2024
- Ray optics and optical instruments
- Let \(\overrightarrow{OP}=\frac{\alpha-1}{\alpha}\hat{i}+\hat{j}+\hat{k},\overrightarrow{OQ}=\hat{i}+\frac{\beta-1}{\beta}\hat{j}+\hat{k}\) and \(\overrightarrow{OR}=\hat{i}+\hat{j}+\frac{1}{2}\hat{k}\) be three vector where α, β ∈ R - {0} and 0 denotes the origin. If \((\overrightarrow{OP}\times\overrightarrow{OQ}).\overrightarrow{OR}=0\) and the point (α, β, 2) lies on the plane 3x + 3y - z + l = 0, then the value of l is _______.
- JEE Advanced - 2024
- Vector Algebra
- Let \(\vec{p}=2\hat{i}+\hat{j}+3\hat{k}\) and \(\vec{q}=\hat{i}-\hat{j}+\hat{k}\). If for some real numbers α, β and γ we have
\(15\hat{i}+10\hat{j}+6\hat{k}=α(2\vec{p}+\vec{q})+β(\vec{p}-2\vec{q})+γ(\vec{p}\times\vec{q})\),
then the value of γ is ________.- JEE Advanced - 2024
- Vector Algebra
View More Questions
Concepts Used:
Coordination Compounds
A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.
Coordination entity:
A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.
Ligands:
A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.
SUBSCRIBE TO OUR NEWS LETTER
COLLEGE NOTIFICATIONSEXAM NOTIFICATIONSNEWS UPDATES
Download the Collegedunia app on 
© 2024 Collegedunia Web Pvt. Ltd. All Rights Reserved