Question:

Structure anions of acids, $ HNO_{3}, H_{3}PO_{4} $ and $ H_{2}SO_{4} $ are, respectively

Updated On: Jun 14, 2022
  • tetrahedral, tetrahedral and trigonal bipyramidal
  • angular, tetrahedral and trigonal bipyramidal
  • tetrahedral, tetrahedral and angular
  • planar, tetrahedral and tetrahedral
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The Correct Option is D

Solution and Explanation

Anions of the acids $HNO_{3}, H_{3}PO_{4}$ and $H_{2}SO_{4}$ are $NO^{-}_{3}, PO^{3-}_{4}$ and $SO^{2-}_{4}$ respectively
Their structures can be explained as follows:
$NO^{-}_{3}$ has planar structure It has nitrogen as a central atom without lone pair, whidi is bonded to three oxygen atoms. Its hybridisation can be predicted by $\frac{1}{2}[V+M-C+A]$
Where $V$ = number of valence electrons
$M$ = number of monovalent ion
$C$= cationic charge
$A$ - anionic charge
$\therefore$ Hybridisation $=\frac{1}{2}[5+0-0+1]=3$

$PO^{3-}_{4}$ has tetrahedral structure. It has phosphorus as a central atom without lone pair which is bonded to four oxygen atoms. Its hybridisation can be predicted as $\frac{1}{2}[5+0-0+3]=3$

$SO^{2-}_{4}$ has tetrahedral structure. It has phosphorus as a central atom without lone pair which is bonded to four oxygen atoms. Its hybridisation can be predicted as
$\frac{1}{2}[6+0-0+2]=4$

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Concepts Used:

Chemical Bonding and Molecular Structure

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Types of Chemical Bonds:

There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds. 

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  • Polar Bonds - In Polar Covalent chemical bonding, electrons are shared unequally since the more electronegative atom pulls the electron pair closer to itself and away from the less electronegative atom.

Factors Affecting Bond Enthalpy in Chemical Bonding:

  • Size of the Atom
  • Multiplicity of Bonds
  • Number of Lone Pair of Electrons Present
  • Bond Angle