For a first-order reaction:
\[ t_{1/2} = 120 \, \text{min} \]For 90% completion:
\[ t = \frac{2.303}{k} \log \left( \frac{a}{a - x} \right) \] \[ t = \frac{2.303 \times 120}{0.693} \log \left( \frac{100}{10} \right) \] \[ t = 399 \, \text{min}. \]A[M] | B[M] | initial rate of formation of D | |
I | 0.1 | 0.1 | 6.0 × 10-3 |
II | 0.3 | 0.2 | 7.2 × 10-2 |
III | 0.3 | 0.4 | 2.88 × 10-1 |
IV | 0.4 | 0.1 | 2.40 × 10-2 |