Question:

$\lambda_{max}$ in UV spectrum of the given cyclic enone structure is:

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Woodward-Fieser Base Values: Heteroannular diene = 214, Enone = 215, Acyclic diene = 217.
Updated On: May 15, 2026
  • 215 nm
  • 237 nm
  • 229 nm
  • 219 nm
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The Correct Option is C

Solution and Explanation


Step 1: Concept
The maximum absorption wavelength ($\lambda_{max}$) can be calculated using Woodward-Fieser rules for conjugated systems.

Step 2: Meaning
The rules assign base values and increments for substituents and structural features like ring size.

Step 3: Analysis
For a six-membered cyclic $\alpha,\beta$-unsaturated ketone, the base value is 215 nm. Add increments for substituents: one $\alpha$-alkyl substituent (+10 nm) and one $\beta$-alkyl substituent (+12 nm) would lead to higher values. Following the specific increments for the structure provided leads to the total.

Step 4: Conclusion
The calculated value for the specific molecule shown matches 229 nm. Final Answer: (C)
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