Question:

Find the product X, Y in the following reaction:

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High-temperature rearrangements of nitrogen heterocycles often lead to substituted aniline derivatives.
Updated On: May 15, 2026
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The Correct Option is B

Solution and Explanation


Step 1: Concept
This involves the thermal rearrangement of quinazoline derivatives followed by nucleophilic substitution.

Step 2: Meaning
At high temperatures ($400^{\circ}C$), certain heterocyclic systems undergo ring opening or rearrangement to form more stable aromatic intermediates.

Step 3: Analysis
Heating the starting material causes a structural transition to intermediate X, which is an o-amino-N-methylaniline derivative. Treatment with a thiol (R-SH) then results in the displacement of functional groups to form the final dithioether Y.

Step 4: Conclusion
The structures for X and Y identified in option 2 match the expected chemical behavior of this pathway. Final Answer: (2)
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