The solution to the given problem involves understanding the concepts of Linear Programming Problems (LPP) and feasible regions.
Assertion (A): Every point of the feasible region of a Linear Programming Problem is an optimal solution.
The feasible region of an LPP is the set of all points that satisfy the constraints of the problem. However, for an LPP, the optimal solution does not occur at every point within this region. Instead, it is typically found at the vertices, or corner points, of the feasible region. Therefore, the assertion that every point is an optimal solution is incorrect.
Reason (R): The optimal solution for a Linear Programming Problem exists only at one or more corner point(s) of the feasible region.
This statement is true. In the context of LPPs, according to the "Fundamental Theorem of Linear Programming," if there exists an optimal solution, it will occur at one of the corner points (vertices) of the feasible region. Therefore, this reason accurately describes where optimal solutions are located within the feasible region.
Upon examination:
The correct option is: Assertion (A) is false but Reason (R) is true.
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]
Write chemical equations of the following reactions:
(i) Phenol is treated with conc. HNO\(_3\)
(ii) Propene is treated with B\(_2\)H\(_6\) followed by oxidation by H\(_2\)O\(_2\)/OH\(^-\)
(iii) Sodium t-butoxide is treated with CH\(_3\)Cl