Question:

A compound with molecular mass $180$ is acylated with $CH_3COCl$ to get a compound with molecular mass $390$. The number of amino groups present per molecule of the former compound is

Updated On: Oct 10, 2024
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The Correct Option is B

Solution and Explanation

Since each - $COCH_3$ group displace one H atom in the reaction molecular mass increases with 42 unit.
Since the mass increases by (390 - 180) = 210, hence the number of - $NH_2$ group is $=\frac{210}{42}=5$.
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Concepts Used:

Amines

Amine is a type of compound which is derived from ammonia (NH3). According to Organic chemistry, they are basically classified as the functional groups of the organic nitrogen compounds that contain nitrogen atoms with a lone pair.

Amine - Types

Primary Amines:

It is formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group. Amino acids and methyl amine are the best examples that why aromatic amines include aniline.

Secondary Amines:

Amines that have two organic substitutes either alkyl or aryl ones or both and are bound to the nitrogen together with one hydrogen are termed as secondary amines. For Example, Dimethylamine.

Tertiary Amines:

Tertiary Amines are the amines where the nitrogen consists of three organic substitutes. For example, Trimethylamine and EDTA.