List of top Inorganic Chemistry Questions asked in Indian Institute Of Technology Joint Admission Test for MSc

Among [Ti(H2O)₆]³⁺,[NiCl₄]²⁻,[CrO₄]²⁻,and [Mn(H₂O)₆]²⁺, the complex that exhibits the largest molar absorptivity in the visible region of the electronic absorption spectrum is

[Co(NH₃)₅(SO₄)]Br and [Co(NH₃)₅Br]SO₄ are examples of

Zn–C bond polarity in the compounds below

follows the order

Elements and their processes of extraction/purification are given. The correct pair(s) is/are

The magnetic moment of O₃ molecule is _______ Bohr magneton (B.M.). (rounded off to the nearest integer)

The correct statement(s) about the ligand substitution/exchange reaction is/are

For the reaction shown below

the oxidation states of Mn in P and Q, respectively, are

The bond length of CO is 113 pm and its dipole moment (𝜇⃗) is 0.1 D. The charge (in units of electronic charge) on carbon in the CO molecule including its sign is (rounded off to three decimal places)
[Given: charge of electron = 1.602×10⁻¹⁹ C; 1 D=3.336 × 10⁻³⁰ Cm]

The number and nature of d−d transition(s) in the case of Sc²⁺ in an octahedral crystal field, respectively, are
[Ignore spin-orbit coupling and Jahn-Teller distortion.]

The d-d transitions in [Mn(H2O)6]²⁺ and [Ti(H2O)4]³⁺ , respectively, are [Ignore spin-orbit coupling and Jahn-Teller distortion.]

The N–O bond order in [NO]⁻ is _______

The metal ion present in human carbonic anhydrase is

The oxoacid of sulfur that has S-O-S bond is

Free heme in aqueous solution when exposed to dioxygen is finally converted to (circle around iron in the given choices represents the protoporphyrin IX)

The role(s) of fluorspar in the electrolytic reduction of Al₂O₃ is/are to

The transition metal (M) complex that can have all isomers (geometric, linkage, and ionization) is

In a gravimetric estimation of Al, a sample of 0.1000 g AlCl₃ is precipitated with 8-hydroxyquinoline. The weight of the precipitate is _____ g.
[Given: atomic weight of Al is 26.98; molecular weight of AlCl₃ is 133.34; and molecular weight of 8-hydroxyquinoline is 145.16] 
(round off to 4 decimal places)

The correct order of the energy of the d orbitals of a square planar complex is

The correct order of energy levels of the molecular orbitals of N₂ is

The geometry of [VO(acac)₂] is

The number of valence electrons in Na₂[Fe(CO)₄] (the Colman’s reagent) is _____.

The correct statement(s) about the complexes I (K3[CoF₆]) and II (K₃[RhF₆]) is/are

The diatomic molecule(s) that has/have bond order of one is/are

The spin-only magnetic moment of [Fe(acac)₃] is____μ𝐵 .
(round off to two decimal places)

The structure types of B10H10 2- and B10H14 respectively, are