List of top Chemistry Questions on Equilibrium

The equilibrium constant for the reaction
\( \text{SO}_3 \, (g) \rightleftharpoons \text{SO}_2 \, (g) + \frac{1}{2} \text{O}_2 \, (g) \)
is \( K_C = 4.9 \times 10^{-2} \). The value of \( K_C \) for the reaction given below is
\( 2 \text{SO}_2 \, (g) + \text{O}_2 \, (g) \rightleftharpoons 2 \text{SO}_3 \, (g) \) is

\( A_{(g)} \rightleftharpoons B_{(g)} + \frac{C}{2}_{(g)} \) The correct relationship between \( K_P \), \( \alpha \), and equilibrium pressure \( P \) is:

For the reaction \( \text{N}_2\text{O}_4(g) \rightleftharpoons 2\text{NO}_2(g) \), \( K_p = 0.492 \, \text{atm} \) at 300 K. \( K_c \) for the reaction at the same temperature is _____ \( \times \, 10^{-2} \).
(Given: \( R = 0.082 \, \text{L atm mol}^{-1} \text{K}^{-1} \))

Consider the following reaction in a sealed vessel at equilibrium with concentrations of
N₂ = 3.0 × 10^–3 M, O₂ = 4.2 × 10^–3 M and NO = 2.8 × 10^–3 M.
2NO_(g)⇋N2(g) + O_2(g) 
If 0.1 mol L^–1 of NO_(g) is taken in a closed vessel, what will be degree of dissociation (a) of NO_(g) at equilibrium?

Which of the following could not be a rate determining step?

600 mL of 0.04 M HCl is mixed with 400 mL of 0.02 M H₂SO₄. Find out the pH of resulting solution (Nearest integer).

The decomposition of CaCO3 in a closed vessel is represented by the equation
CaCO₃ ⇌ (s) CaO (s) + CO₂ (g)
Calculate the number of phases, components and degree of freedom

For the reaction
2N₂O₅→4NO₂+0₂
Rate of the reaction is:

25% of a first order reaction completes in \(2.1 \times 10^6\) s. How much time is required to complete the reaction?

For a cell involving one electron \(E^\ominus cell=0.59V\) at 298 K, the equilibrium constant for the cell reaction is: [Given that \(\frac{ 2.303 RT }{F}\) \(=0.059 V\) at\( T 298 K \)] 

KMnO₄ can be prepared from K₂MnO₄ as per the reaction:
\(3MnO^{2-}_4+2H_2O⇌2MnO^-_4+MnO_2+4OH^-\)
The reaction can go to completion by removing OH^- ions by adding

The correct order of acid strength is

What is the correct relationship between the pH_s of isomolar solutions of sodium oxide (pH₁),sodium sulphide (pH₂),sodium selenide (pH₃) and sodium telluride (pH₄)?

H₂S gas when passed through a solution of cations containing HCl precipitates the cations of second group of qualitative analysis but not those belonging to the fourth group. It is because:

Equilibrium constants K₁ and K₂ for the following equilibria: NO_(g)+\(\bigg(\frac{1}{2}\bigg)\)O₂ \(^{K_1}_\rightleftharpoons\) NO₂(g) and 2NO_2(g) \(^{K_2}_\rightleftharpoons\) 2NO_(g)+O_2(g) are related as:

The reaction quotient (Q) for the reaction \(N_2(g) + 3H_2(g)⇋2NH_3(g)\) is given by \(Q =\frac { [NH_3]^2}{[N_2][H_2]^3}\). The reaction will proceed from right to left if: (where K_C is the equilibrium constant)

The solubility product of AgI at 25ºC is 1.0×10^–16 mol²L^–2. The solubility of AgI in 10^–4N solution of KI at 25ºC is approximately (in mol L^–1):

For a any reversible reaction. If increases concentration of reactants. Then effect on equilibrium constant:

Correct relation b/w dissociation constant's of a di-basic acid:

At equilibrium the concentrations of ${\mathrm{N}}_2=3.0\times {10}^{-3}\mathrm{M},{\mathrm{O}}_2=4.2\times {10}^{-3}\mathrm{M}$ and $\mathrm{NO}=2.8\times {10}^{-3}\mathrm{M}$ in a sealed vessel at $800\mathrm{K}$. What will be ${\mathrm{K}}_{\mathrm{C}}$ for the reaction ${\mathrm{N}}_{2(\mathrm{g})}+{\mathrm{O}}_{2(\mathrm{g})}\leftrightharpoons 2{\mathrm{NO}}_{(\mathrm{g})}?$