Step 1: Understanding the Question:
We need to identify the single monomer starting material used to synthesize the polymer Nylon-6.
Step 2: Detailed Explanation:
Nylon-6 is a synthetic polyamide polymer.
It is synthesized by heating caprolactam with water at a high temperature (around $533\text{-}543\ \text{K}$).
Under these conditions, the seven-membered caprolactam ring opens up to form aminocaproic acid, which then undergoes continuous condensation polymerization to form the long chains of Nylon-6.
The "6" in its name specifically indicates that the monomer, caprolactam, contains exactly six carbon atoms.
Step 3: Final Answer:
The monomer used is caprolactum, matching option (C).