Question:

Which of the following is the most acidic carboxylic acid:

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More Carbon chains = More +I effect = Less Acidic. Formic is the simplest and strongest.
Updated On: May 25, 2026
  • Formic acid
  • Butanoic acid
  • Acetic acid
  • Propanic acid
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The Correct Option is A

Solution and Explanation

Step 1: Concept
The acidity of carboxylic acids is influenced by the inductive effect of the attached alkyl groups.

Step 2: Meaning

Alkyl groups have a +I (electron-donating) effect, which destabilizes the carboxylate anion and decreases acidity.

Step 3: Analysis

Formic acid (HCOOH) has only a hydrogen atom attached. Acetic, Propanoic, and Butanoic acids have methyl, ethyl, and propyl groups respectively, which decrease acidity via the +I effect.

Step 4: Conclusion

Formic acid is the strongest acid among the given options because it lacks electron-donating alkyl groups. Final Answer: (A)
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