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Organic Chemistry
List of top Organic Chemistry Questions
The reaction(s) that yield(s) X as the major product is (are)
GATE CY - 2024
GATE CY
Organic Chemistry
Identification of products, intermediates and isotopic labelling
A reaction of 10.50 g of 1,2-diphenylethane-1,2-dione with conc. NaOH followed by aqueous acidic work-up furnished 8.55 g of a carboxylic acid. The yield of the carboxylic acid in this reaction is _______ %.
(rounded off to the nearest integer)
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The specific rotation of an optically pure compound is +75.3 (c 1.0 in CHCl
3
) at 20 °C. A synthetic sample of the same compound showed a specific rotation of +66.3 (c 1.0 in CHCl
3
) at 20 °C. The enantiomeric excess (ee) of the synthetic sample is _______ %.
(rounded off to the nearest integer)
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Stereochemistry
Consider the following
1
H-NMR (400 MHz, DMSO-d
6
) data of a compound :
δ in ppm: 3.85 (s, 6H), 6.73 (t, J = 2.2 Hz, 1H), 7.1 (d, J = 2.2 Hz, 2H), and 13.05 (brs, 1H).
The compound is
GATE CY - 2024
GATE CY
Organic Chemistry
NMR and ESR spectroscopy
The acidity of the compounds shown below
follows the order
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Heterocyclic Chemistry
The suitable synthetic route(s) for the following transformation
is/are
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The pair of proteins having heme core is
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Natural Products Chemistry
The major products X and Y in the following reactions
respectively, are
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Qualitative Organic Analysis
The suitable reagent combination for the following transformation
is
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
Among the following, the chiral molecule(s) is/are
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Stereochemistry
Exhaustive hydrogenation of the following compound
under Pd/C generates a saturated hydrocarbon as the product.
The number of stereoisomers possible for this product is _______.
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Stereochemistry
The major product formed in the following reaction
is
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The compound(s) which on reaction with CH
3
MgBr followed by treatment with aqueous NH
4
Cl would produce 1-methyl-1-phenylethanol as the major product is/are
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The major product formed in the following reaction Me Me ONO Me
is
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
In the following reaction
optically pure ester X formed product that did not exhibit optical rotation ([α]D=0) due to the formation of
(Note: Ts=para-toluenesulfonyl; Ac=acetyl)
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Stereochemistry
Among the following, the compound(s) which produce the same osazone as that obtained from D-glucose, when reacted with phenylhydrazine, is/are
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The major product formed in the following reaction
is.
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Reaction Mechanisms & Synthesis
The following dipeptide derivative is used as an artificial sweetener:
The constituent α-amino acids of this dipeptide are
IIT JAM CY - 2024
IIT JAM CY
Organic Chemistry
Natural Products Chemistry
In the given reaction sequence, the amount of R produced (in g) is ______.
(Given: molar mass (in g mol
-1
) of H = 1, C = 12, N = 14, O = 16, and S = 32)
(rounded off to two decimal places)
GATE CY - 2024
GATE CY
Organic Chemistry
Basic mechanistic concepts
Which of the following is a meta directing group:
GPAT - 2024
GPAT
Organic Chemistry
carbonyl compounds
The IUPAC name of tartaric acid is:
GPAT - 2024
GPAT
Organic Chemistry
Heterocyclic Chemistry
In which limit test, Thioglycolic acid is used:
GPAT - 2024
GPAT
Organic Chemistry
Organic Chemistry- Some Basic Principles and Techniques
The starting raw material for synthesis of lignocaine is:
GPAT - 2024
GPAT
Organic Chemistry
Amino Acids
How many optical isomers are possible for lactic acid:
GPAT - 2024
GPAT
Organic Chemistry
Stereochemistry
Which functional group in drug molecules is most likely to undergo phase I metabolic oxidation by cytochrome P450 enzymes:
GPAT - 2024
GPAT
Organic Chemistry
carbonyl compounds
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