Question:

Which of the following displaces $Br _{2}$ from an aqueous solution containing bromide ions?

Updated On: Jun 14, 2022
  • $ Cl^{-} $
  • $ Cl_{2} $
  • $I _{3}^{-}$
  • $ I_{2} $
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The Correct Option is B

Solution and Explanation

All the halogens act as strong oxidising agents since, they have a strong tendency to attract electrons. The oxidising power decreases from $F$ to $I$.
ie, $ F _{2}> Cl _{2}> Br _{2}> I _{2}$.
So, $Cl _{2}$ will displace $Br ^{-}$and $I ^{-}$ions from their solutions.
$Cl _{2}+2 Br ^{-} \longrightarrow Br _{2}+2 Cl ^{-} .$
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Concepts Used:

Group 17 Elements

Halogens are the group 17 elements of the periodic table. The term ‘halogen’ means ‘salt-producing’, hence the name halogens as they possess the tendency to form salts after reacting to metals. It generally has five elements:

  • Fluorine (F)
  • Chlorine (Cl)
  • Bromine (Br)
  • Iodine (I)
  • Astatine (At)

These are all naturally occurring halogens but Tennessine (Ts) is an artificially created halogen.

Halogens:

Halogens are highly reactive elements and are highly electronegative. They have a high tendency to react with metals to form salts. They are also known as Group 17 elements. They have 7 electrons in their outer shell with a configuration of (ns2 np5). Fluorine being the first halogen in group 17, is highly reactive. Astatine is a halogen because of its resemblance with iodine despite it being radioactive.

Electronic Configuration:

The general electronic configuration for group 17 elements is ns2np5. This configuration clearly shows that they have 7 electrons in their valence shell. They require one more electron to complete their octet and achieve noble gas configuration.