Question:

The transition metal having highest \(3^\text{rd}\) ionisation enthalpy is:

Updated On: Nov 27, 2024
  • Cr
  • Mn
  • V
  • Fe
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The Correct Option is B

Solution and Explanation

The 3rd ionisation enthalpy refers to the energy required to remove the third electron after the removal of the first and second electrons from a neutral atom.
Reasoning for Mn Having the Highest 3rd Ionisation Enthalpy
Manganese (Mn) has the electronic configuration [Ar] $3d^5 4s^2$.
The removal of the first and second electrons leads to a half-filled $3d^5$ configuration, which is highly stable due to symmetrical distribution and exchange energy.
Removing the third electron from this stable half-filled $3d^5$ configuration requires a significantly higher amount of energy compared to other transition elements such as Cr, V, and Fe.
Conclusion: The transition metal having the highest 3rd ionisation enthalpy is Mn.

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