(a) Since, change of state $(p_1, V_1 , T_1) \, to \, (p_2, V_2, T_2)$ is isothermal therefore, $T_3 < T_2$.
(b) Since, change of state $(p_1, V_1 , T_1,) \, to \, (p_3, V_3, T_3)$ is an adiabatic expansion it brings about cooling of gas, therefore, $T_3 < T_1$
(c) Work done is the area under the curve of p-V diagram. As obvious from the given diagram, magnitude of area under the isothermal curve is greater than the same under adiabatic curve, hence $W_{isothermal} > W_{adiabatic}$
(d) $?U = nC_u?T$
In isothermal process, $?U = 0 \, as \, ?T = 0$
In adiabatic process. $?U = nC_p,(T_3 - T_1 ) < 0 \, as \, T_3 < T_1 $.
$ \Rightarrow \, \, \, \, \, ?U_{isotherml} > ?U_{adiabatic} $
NOTE Here only magnitudes of work is being considered otherwise both works have negative sign.