The quantity which changes with temperature:
- Mole fraction
- Mass Percentage
- Molarity
- Molality
The Correct Option is C
Solution and Explanation
Top Questions on Laws of thermodynamics
- Which one of the following statements is correct in the context of thermodynamics?
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- Consider the following volume−temperature (V−T) diagram for the expansion of 5 moles of an ideal monoatomic gas.
Considering only P-V work is involved, the total change in enthalpy (in Joule) for the transformation of state in the sequence X→Y→Z is ______.
[Use the given data: Molar heat capacity of the gas for the given temperature range, CV,m = 12 J K−1mol−1 and gas constant, R=8.3 JK−1 mol−1]- JEE Advanced - 2024
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- Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R
Assertion A: In an Ellingham diagram, the oxidation of carbon to carbon monoxide shows a negative slope with respect to temperature
Reason R: CO tends to get decomposed at higher temperature
In the light of the above statements, choose the correct answer from the options given below- JEE Main - 2023
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- A certain amount of gas of volume $V$ at $27^{\circ} C$ temperature and pressure $2 \times 10^7 Nm ^{-2}$ expands isothermally until its volume gets doubled Later it expands adiabatically until its volume gets redoubled The final pressure of the gas will be (Use $\gamma=15$ )
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- How many reactions are non-spontaneous at 300 K. For independent reaction ΔH & ΔS values are given.
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Questions Asked in JEE Main exam
- Find the acceleration of \(2\) \(kg\) block shown in the diagram (neglect friction)
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- Let \(α\) and \(β\) the roots of equation \(px^2 + qx - r = 0\), where \(P≠ 0\). If \(p,q,r\) be the consecutive term of non constant G.P and \(\frac{1}{α} + \frac{1}{β} = \frac{3}{4}\) then the value of \((α - β)^2\) is:
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- Two lines \(L_1 \;\& \;L_2\) passing through origin trisecting the line segment intercepted by the line \(4x + 5y = 20\) between the coordinate axes. Then the tangent of angle between the lines \(L_1\) and \(L_2\) is
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- permutations and combinations
Concepts Used:
Thermodynamics
Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.
Important Terms
System
A thermodynamic system is a specific portion of matter with a definite boundary on which our attention is focused. The system boundary may be real or imaginary, fixed or deformable.
There are three types of systems:
- Isolated System – An isolated system cannot exchange both energy and mass with its surroundings. The universe is considered an isolated system.
- Closed System – Across the boundary of the closed system, the transfer of energy takes place but the transfer of mass doesn’t take place. Refrigerators and compression of gas in the piston-cylinder assembly are examples of closed systems.
- Open System – In an open system, the mass and energy both may be transferred between the system and surroundings. A steam turbine is an example of an open system.
Thermodynamic Process
A system undergoes a thermodynamic process when there is some energetic change within the system that is associated with changes in pressure, volume and internal energy.
There are four types of thermodynamic process that have their unique properties, and they are:
- Adiabatic Process – A process in which no heat transfer takes place.
- Isochoric Process – A thermodynamic process taking place at constant volume is known as the isochoric process.
- Isobaric Process – A process in which no change in pressure occurs.
- Isothermal Process – A process in which no change in temperature occurs.
Laws of Thermodynamics
Zeroth Law of Thermodynamics
The Zeroth law of thermodynamics states that if two bodies are individually in equilibrium with a separate third body, then the first two bodies are also in thermal equilibrium with each other.
First Law of Thermodynamics
The First law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.
Second Law of Thermodynamics
The Second law of thermodynamics is a physical law of thermodynamics about heat and loss in its conversion.
Third Law of Thermodynamics
Third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: The entropy of a system approaches a constant value when its temperature approaches absolute zero.
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