Question:

The oxidation number of Pt in [Pt(en)2Cl2]2+ is :

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en is neutral (0); each Cl is -1; sum of charges must equal the +2 on the ion.
Updated On: Jun 15, 2026
  • + 3
  • + 4
  • + 2
  • + 6
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The Correct Option is B

Solution and Explanation

Concept: Overall charge = (oxidation number of metal) + (sum of ligand charges).
Step 1: Ethylenediamine (en) is a neutral bidentate ligand, charge 0; each chloride is \(-1\), so two give \(-2\).
Step 2: Let Pt be \(x\). The complex ion carries \(+2\):
\[x + 2(0) + 2(-1) = +2 \Rightarrow x - 2 = +2 \Rightarrow x = +4\]Answer: \(\boxed{+4}\), option (B).
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