Question:

The oxidation number of Co in [Co(NH$_3$)$_5$(ONO)]SO$_4$ is :

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Neutral ligands such as NH$_3$, H$_2$O and CO contribute zero charge while calculating oxidation state.
Updated On: Jun 29, 2026
  • +3
  • +2
  • +4
  • +6
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The Correct Option is A

Solution and Explanation

Concept: Sum of oxidation numbers of all atoms in a complex ion equals the charge on the complex ion.

Step 1: Identify ligand charges. \[ NH_3 \] is neutral. \[ ONO^- \] has charge \[ -1 \] Sulphate ion outside bracket: \[ SO_4^{2-} \] Therefore complex ion must have charge \[ +2 \]

Step 2: Let oxidation state of cobalt be x. \[ x+5(0)+(-1)=+2 \] \[ x-1=2 \] \[ x=3 \]

Step 3: Final answer. \[ \boxed{+3} \] Hence option (A) is correct.
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