The osmotic pressure of solutions of PVC in cyclohexanone at $300 K$ are plotted on the graph The molar mass of $PVC$ is ____$g \,mol ^{-1}$ (Nearest integer)
( Given : R = 0.083 L atm K-1 mol-1 )
( Given : R = 0.083 L atm K-1 mol-1 )
Correct Answer: 41500
Approach Solution - 1
The correct answer is 41500
If we assume graph between and
Assuming vs graph
Slope
Approach Solution -2
The van 't Hoff equation for osmotic pressure (\(\pi\)) is:
\[ \pi = CRT \]
Dividing both sides by concentration (\(C\)):
\[ \frac{\pi}{C} = RT \times \frac{1}{M} \]
From the graph, the slope (\(\frac{\pi}{C}\)) is determined to be 6.0 atm L g$^{-1}$.
Using the relation: \[ M = \frac{RT}{\text{slope}} \]
Substituting the values:
\[ M = \frac{0.083 \times 300}{6.0} = 41500 \, \text{g mol$^{-1}$}. \]
Thus, the molar mass of PVC is 41500 g \(mol^{-1}\).
The molar mass of a polymer like PVC can be calculated from osmotic pressure data using the van 't Hoff equation. The slope of the \(\pi / C\) graph provides critical information for this calculation.
Top JEE Main Chemistry Questions
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)- At equilibrium the concentrations of and in a sealed vessel at . What will be for the reaction
- Find out the major products from the following reactions
Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
- The correct order of atomic radii is:
Top JEE Main Solutions Questions
- What weight of glucose must be dissolved in 100 g of water to lower the vapour pressure by 0.20 mm Hg?
(Assume dilute solution is being formed)
Given : Vapour pressure of pure water is 54.2 mm Hg at room temperature. Molar mass of glucose is 180 g mol–1 . - Solubility of \(Ca_3(PO_4)_2\) in \(100\) \(mL\) of pure water is \(W\) gm. Find out \(K_{sp}\) of \(Ca_3(PO_4)_2\) is: (M: Molecular mass of \(Ca_3(PO_4)_2\))
- We are given with three NaCl samples and their Van't Hoff factors. Which is correct option ?
Sample Van't Haff Factor Sample - 1 (0.1 M) \(i_1\) Sample - 2 (0.01 M) \(i_2\) Sample - 3 (0.001 M) \(i_2\) - Ethylene glycol of \(x\) \(kg\) is mixed with \(18.6\) \(kg\) of solvent, \(24 °C\) depression in freezing point takes place. Calculate value of \(x\). (Given: \(K_1\) = \(1.6 °C/molal\) M.W. of ethylene glycol = \(62\) \(g/mol\))
- $\text{Volume of } 3 \, \text{M NaOH (formula weight 40 g mol}^{-1}\text{) which can be prepared from } 84 \, \text{g of NaOH is } \_\_\_\_\_ \times 10^{-1} \, \text{dm}^3.$
Top JEE Main Questions
- Two masses $m$ and $\frac{m}{2}$ are connected at the two ends of a massless rigid rod of length $l$. The rod is suspended by a thin wire of torsional constant $k$ at the centre of mass of the rod-mass system(see figure). Because of torsional constant $k$, the restoring torque is $\tau =k\theta$ for angular displacement $\theta$. If the rod is rota ted by $\theta_0$ and released, the tension in it when it passes through its mean position will be:
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)- The value of is
- The number of terms of an is even. The sum of the odd terms is and of the even terms is . The last term exceeds the first by . Then the number of terms in the series is ______.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,
Concepts Used:
Solutions
A solution is a homogeneous mixture of two or more components in which the particle size is smaller than 1 nm.
For example, salt and sugar is a good illustration of a solution. A solution can be categorized into several components.
Types of Solutions:
The solutions can be classified into three types:
- Solid Solutions - In these solutions, the solvent is in a Solid-state.
- Liquid Solutions- In these solutions, the solvent is in a Liquid state.
- Gaseous Solutions - In these solutions, the solvent is in a Gaseous state.
On the basis of the amount of solute dissolved in a solvent, solutions are divided into the following types:
- Unsaturated Solution- A solution in which more solute can be dissolved without raising the temperature of the solution is known as an unsaturated solution.
- Saturated Solution- A solution in which no solute can be dissolved after reaching a certain amount of temperature is known as an unsaturated saturated solution.
- Supersaturated Solution- A solution that contains more solute than the maximum amount at a certain temperature is known as a supersaturated solution.