The kinetic energies of an electron (\(e\)) and a proton (\(p\)) are \(E\) and \(3E\), respectively. Given that the mass of a proton is 1836 times that of an electron, the ratio of their de Broglie wavelengths (\(\lambda_e / \lambda_p\)) is ___________ (rounded off to two decimal places).
The de Broglie wavelength (\(\lambda\)) of a particle is given by the equation: \[ \lambda = \frac{h}{p} \] where \(h\) is Planck's constant and \(p\) is the momentum of the particle. The kinetic energy (\(K\)) of a particle is related to its momentum by: \[ K = \frac{p^2}{2m} \implies p = \sqrt{2mK} \] where \(m\) is the mass of the particle. For the electron (\(e\)), the kinetic energy is \(K_e = E\) and its mass is \(m_e\). The de Broglie wavelength of the electron is: \[ \lambda_e = \frac{h}{p_e} = \frac{h}{\sqrt{2m_e K_e}} = \frac{h}{\sqrt{2m_e E}} \] For the proton (\(p\)), the kinetic energy is \(K_p = 3E\) and its mass is \(m_p = 1836 m_e\). The de Broglie wavelength of the proton is: \[ \lambda_p = \frac{h}{p_p} = \frac{h}{\sqrt{2m_p K_p}} = \frac{h}{\sqrt{2(1836 m_e) (3E)}} = \frac{h}{\sqrt{11016 m_e E}} \] Now, we need to find the ratio of their de Broglie wavelengths (\(\lambda_e / \lambda_p\)): \[ \frac{\lambda_e}{\lambda_p} = \frac{\frac{h}{\sqrt{2m_e E}}}{\frac{h}{\sqrt{11016 m_e E}}} = \frac{\sqrt{11016 m_e E}}{\sqrt{2m_e E}} = \sqrt{\frac{11016 m_e E}{2m_e E}} \] \[ \frac{\lambda_e}{\lambda_p} = \sqrt{\frac{11016}{2}} = \sqrt{5508} \] \[ \sqrt{5508} \approx 74.2159 \] Rounding off to two decimal places, the ratio \(\lambda_e / \lambda_p\) is 74.22. This falls within the given range of 74.10 to 74.30.
The Lineweaver-Burk plot for an enzyme obeying the Michaelis-Menten mechanism is given below. 
The slope of the line is \(0.36 \times 10^2\) s, and the y-intercept is \(1.20\) mol\(^{-1}\) L s. The value of the Michaelis constant (\(K_M\)) is ________ \( \times 10^{-3} \) mol L\(^{-1}\) (in integer). [Note: \(v\) is the initial rate, and \([S]_0\) is the substrate concentration]
The expressions for the vapour pressure of solid (\( p_1 \)) and vapour pressure of liquid (\( p_2 \)) phases of a pure substance, respectively, are \[ \ln p_1 = \frac{-2000}{T} + 5 \quad {and} \quad \ln p_2 = \frac{-4000}{T} + 10 \] The triple point temperature of this substance is __________ K (in integer).
The specific rotation of enantiomerically pure (S)-2-butanol is \( +14^\circ \). The specific rotation of the enantiomeric mixture of 2-butanol obtained from an asymmetric reduction of 2-butanone is found to be \( +7^\circ \). The percentage of (R)-2-butanol present in the reaction mixture is ____________ (in integer).}
Partial hydrolysis of a pentapeptide yields all possible tripeptides and dipeptides. The dipeptides that are obtained upon hydrolysis are given below: Val-Ala Gln-His Phe-Val Ala-Gln
The total number of tripeptides obtained that contain ‘Ala’ as one of the amino acids is __________