The incorrect statement regarding the reaction given below is
- The product 'B' formed in the above reaction is p-nitroso compound at low temperature.
- The reaction occurs at low temperature
- The electrophile involved in the reaction is NO+
- 'B' is N-nitroso ammonium compound
The Correct Option is D
Solution and Explanation
Given the reaction of N,N-dimethylaniline ('A') with NaNO2 and HX to form 'B', the correct statements are:
(1) The electrophile involved in the reaction is NO+.
(3) The reaction occurs at low temperature.
(4) The product 'B' formed in the above reaction is p-nitroso compound at low temperature.
Explanation:
* The reaction is a diazotization reaction specific to tertiary aromatic amines.
* NaNO2 and HX generate the nitrosonium ion (NO+), which is the electrophile.
* Diazotization reactions are performed at low temperatures to prevent decomposition of intermediates.
* The product formed is a p-nitroso compound due to electrophilic aromatic substitution at the para position.
Statement (2) is incorrect because the product is a p-nitroso compound, not an N-nitroso ammonium compound.
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