Match the LIST-I with LIST-II. 
Choose the correct answer from the options given below:
A transition metal (M) among Mn, Cr, Co and Fe has the highest standard electrode potential \( (M^{3+} / M^{2+}) \). It forms a metal complex of the type \( [M(CN)_6]^{4-} \). The number of electrons present in the \( e_g \) orbital of the complex is ________.
Which of the following best represents the temperature versus heat supplied graph for water, in the range of \(-20^\circ\text{C}\) to \(120^\circ\text{C}\)? 