Question:

Metal carbonyls are stable due to

Updated On: Dec 26, 2023
  • $\sigma$-back bonding
  • synergic bonding
  • either (a) or (b)
  • neither (a) nor (b).
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The Correct Option is B

Solution and Explanation

The metal-carbon bond in metal carbonyls possesses both $\sigma$ and $\pi$-characters. The ligand to metal is $\sigma$-bond and metal to ligand is back bonding through $\pi$-dative bond. This unique synergic bonding provides stability to metal carbonyls.
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Concepts Used:

Coordination Compounds

A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.

Coordination entity:

A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.

Ligands:

A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.