We need to determine which block of the periodic table each element belongs to based on its electron configuration.
A. Cd (Cadmium): The atomic number of Cd is 48. Its electron configuration is [Kr] \(4d^{10} 5s^2\). The last electron enters the d-orbital, so it belongs to the d-block. Thus, A matches with III.
B. Eu (Europium): The atomic number of Eu is 63. It is one of the Lanthanides. Its electron configuration is [Xe] \(4f^7 6s^2\). The differentiating electron enters the f-orbital, so it belongs to the f-block. Thus, B matches with I.
C. Se (Selenium): The atomic number of Se is 34. Its electron configuration is [Ar] \(3d^{10} 4s^2 4p^4\). The last electron enters the p-orbital, so it belongs to the p-block. Thus, C matches with IV.
D. Ba (Barium): The atomic number of Ba is 56. It is an alkaline earth metal. Its electron configuration is [Xe] \(6s^2\). The last electron enters the s-orbital, so it belongs to the s-block. Thus, D matches with II.
Combining these matches, we get: A-III, B-I, C-IV, D-II.