Concept:
A homogeneous system of linear equations has a unique solution if and only if the determinant of the coefficient matrix is non-zero.
Therefore, the system will not have a unique solution when the determinant becomes zero.
Step 1: Write the coefficient matrix.
The given equations are:
\[
x\cos\theta+y\sec\theta=0
\]
\[
x\sin\theta+y\tan\theta=0
\]
Coefficient matrix:
\[
A=
\begin{bmatrix}
\cos\theta & \sec\theta\\
\sin\theta & \tan\theta
\end{bmatrix}
\]
Step 2: Compute the determinant.
\[
|A|
=
\cos\theta\tan\theta
-
\sin\theta\sec\theta
\]
Substituting:
\[
\tan\theta=\frac{\sin\theta}{\cos\theta}
\]
\[
\sec\theta=\frac{1}{\cos\theta}
\]
Hence,
\[
|A|
=
\cos\theta
\left(
\frac{\sin\theta}{\cos\theta}
\right)
-
\sin\theta
\left(
\frac{1}{\cos\theta}
\right)
\]
\[
=
\sin\theta
-
\frac{\sin\theta}{\cos\theta}
\]
\[
=
\frac{\sin\theta(\cos\theta-1)}
{\cos\theta}
\]
Step 3: Set determinant equal to zero.
\[
\frac{\sin\theta(\cos\theta-1)}
{\cos\theta}=0
\]
Since \(\cos\theta\neq0\),
\[
\sin\theta(\cos\theta-1)=0
\]
Therefore,
\[
\sin\theta=0
\]
or
\[
\cos\theta=1
\]
Step 4: Solve the conditions.
From
\[
\sin\theta=0
\]
we obtain
\[
\theta=n\pi
\]
The condition \(\cos\theta=1\) gives
\[
\theta=2n\pi
\]
which is already included in
\[
\theta=n\pi
\]
Therefore,
\[
\boxed{\theta=n\pi}
\]
Hence the system does not possess a unique solution when
\[
\theta\in\{n\pi:n\in\mathbb{Z}\}
\]
Therefore option (A) is correct.