\[ S_1 = \{A = [a_{ij}] \in M : A = A^T \text{ and } a_{ij} \in S, \forall i, j\}, \]
\[ S_2 = \{A = [a_{ij}] \in M : A = -A^T \text{ and } a_{ij} \in S, \forall i, j\}, \]
\[ S_3 = \{A = [a_{ij}] \in M : a_{11} + a_{22} + a_{33} = 0 \text{ and } a_{ij} \in S, \forall i, j\}. \]
\( S_1 \) includes symmetric matrices, so elements above the diagonal determine the matrix. With 5 choices for each, and 6 such positions:
\[ |S_1| = 5^6 \]
\( S_2 \) includes skew-symmetric matrices, non-diagonal elements are independent, and diagonal elements must be 0 (not in \( S \)), invalidating \( S_2 \).
\[ |S_2| = 0 \]
\( S_3 \) must balance the trace to be zero. Choosing two elements freely allows the third to be determined:
\[ |S_3| = 5^2 \times (\text{number of valid third elements}) \]
Using the inclusion-exclusion principle, find \(n(S_1 \cup S_2 \cup S_3)\):
\[ n(S_1 \cup S_2 \cup S_3) = |S_1| + |S_2| + |S_3| - (\text{intersections}) = 125 \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,