In which of the following reactions, major product is matched correctly?




In this question, we are considering nucleophilic substitution reactions.
Let's analyze each option to determine which correctly matches the major product.
1. Option 1: \( O\text{Na}^+ + \text{EtBr} \longrightarrow \text{OMe} \) This reaction is incorrect because the nucleophile \( O\text{Na}^+ \) does not react with \( \text{EtBr} \) to form \( \text{OMe} \).
The product should be \( \text{OEt} \), not \( \text{OMe} \), which is inconsistent with the reaction conditions.
2. Option 2: \( \text{t-ButO}^-\text{Na}^+ + \text{EtBr} \longrightarrow \text{t-ButO}-\text{Et} \) This reaction is incorrect because the nucleophile \( \text{t-ButO}^- \) (tert-butoxide) reacts with \( \text{EtBr} \) to form \( \text{t-ButO}-\text{Et} \), which is correct in terms of nucleophilic substitution, but not the major product expected for this type of reaction.
3. Option 3: \( O\text{Na}^+ + \text{nPrBr} \longrightarrow \text{O-nPr} \) This is the correct answer.
Here, the nucleophile \( O\text{Na}^+ \) reacts with \( \text{nPrBr} \) (n-propyl bromide) in a nucleophilic substitution, displacing the bromide ion and forming the product \( \text{O-nPr} \), which is the expected major product.
4. Option 4: \( \text{Sec ButO}K^+ + \text{EtBr} \longrightarrow \text{Sec But} - \text{OEt} \)
This is incorrect.
The expected product is \( \text{Sec ButO}-\text{Et} \), but the formation of this product is unlikely given the reagents and expected reaction type. Thus, the correct match is Option 3.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)

Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are





What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,