Question:

: In the electrolysis of aqueous $ NaCl $ , $ Na $ is preferentially discharged at mercury cathode forming sodium amalgam. : It is due to the fact that hydrogen has a high over voltage at mercury cathode.

Updated On: Jun 23, 2023
  • If both Assertion and Reason are true and Reason is the correct explanation of Assertion.
  • If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
  • If Assertion is true but Reason is false.
  • If both Assertion and Reason are false.
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The Correct Option is A

Solution and Explanation

In the electrolysis of a $NaCl$, sodium is preferentially discharged at the mercury cathode forming sodium amalgam ( $Na - Hg$ ) due to the fact that hydrogen has a high over voltage at mercury cathode.
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Concepts Used:

Electrolysis

Electrolysis:

Electrolysis is the process by which an element is decomposed and undergoes some chemical change under the influence of any electric current. The first-ever electrolysis was executed out by Sir Humphrey Davey in the year 1808. Electrolysis can occur in both Galvanic cells and Electrolytic cells

Applications of Electrolysis:

  1. Electrolytic cells are used for the production of Hydrogen and Oxygen gas from water.
  2. They are used for the large-scale production of pure metals like sodium, copper, magnesium, etc.
  3. They are used to extract Aluminium from Bauxite.
  4. Electrolytic cells are used for electroplating, a process by which a thin protective layer of one metal is formed over another metal, mostly for protection.
  5. Electrolysis is used for the electrorefining of non-ferrous metals.

Read More: Products of Electrolysis