In a laser,
population inversion is a condition where more electrons are in an excited state than in a lower energy state, enabling
stimulated emission of photons.
Why Between Two Closely Spaced Excited States? - In most practical lasers (like solid-state or gas lasers), population inversion is created between two excited states rather than between an excited state and the ground state.
- Typically, electrons are pumped to a higher excited level and then quickly decay (non-radiatively) to a slightly lower metastable state.
- From this metastable state, they transition to another excited state (not the ground state), emitting coherent photons.
- This technique makes it easier to achieve and maintain population inversion.
Why Other Options Are Incorrect: - (A) Ground state is usually the most populated; achieving inversion with it is difficult.
- (B) Vibrational levels apply to molecular transitions, not standard laser operation.
- (D) While this might seem correct, the key phrase is “closely spaced” — which enables easier and faster transitions.
Hence, for effective laser operation, population inversion is typically achieved between
two closely spaced excited states.