Concept:
Whenever an equation involving \(\sin\theta\) and \(\cos\theta\) is given, we use the fundamental identity
\[
\sin^2\theta+\cos^2\theta=1.
\]
The given linear relation can be combined with this identity to determine the exact values of \(\sin\theta\) and \(\cos\theta\), and hence evaluate \(\tan\theta\).
Step 1: Square the given relation.
Given,
\[
2\cos\theta+3\sin\theta=3.
\]
Squaring both sides,
\[
4\cos^2\theta+9\sin^2\theta+12\sin\theta\cos\theta=9.
\]
Using
\[
\cos^2\theta=1-\sin^2\theta,
\]
we get
\[
4(1-\sin^2\theta)+9\sin^2\theta+12\sin\theta\cos\theta=9.
\]
Therefore,
\[
5\sin^2\theta+12\sin\theta\cos\theta=5.
\]
Step 2: Use the given equation again.
From
\[
2\cos\theta+3\sin\theta=3,
\]
we have
\[
2\cos\theta=3(1-\sin\theta).
\]
Thus,
\[
\cos\theta=\frac{3(1-\sin\theta)}{2}.
\]
Substituting into
\[
\sin^2\theta+\cos^2\theta=1,
\]
\[
\sin^2\theta+\frac{9(1-\sin\theta)^2}{4}=1.
\]
Multiplying by \(4\),
\[
4\sin^2\theta+9(1-2\sin\theta+\sin^2\theta)=4.
\]
\[
13\sin^2\theta-18\sin\theta+5=0.
\]
Factorizing,
\[
(13\sin\theta-5)(\sin\theta-1)=0.
\]
Hence,
\[
\sin\theta=\frac{5}{13}
\quad\text{or}\quad
\sin\theta=1.
\]
Since \(\tan\theta\) is defined, \(\sin\theta=1\) is not possible because then \(\cos\theta=0\).
Therefore,
\[
\sin\theta=\frac{5}{13}.
\]
Step 3: Find \(\cos\theta\).
Using the given equation,
\[
2\cos\theta+3\left(\frac{5}{13}\right)=3.
\]
\[
2\cos\theta=\frac{24}{13}.
\]
\[
\cos\theta=\frac{12}{13}.
\]
Step 4: Calculate \(\tan\theta\).
\[
\tan\theta
=
\frac{\sin\theta}{\cos\theta}
=
\frac{\frac{5}{13}}{\frac{12}{13}}
=
\frac{5}{12}.
\]
Conclusion:
\[
\boxed{\tan\theta=\frac{5}{12}}
\]