Given, $E^\circ _{Cr ^{3+}/Cr} =-0.74\, V;E^\circ_{MnO^-_4/Mn^{2+}}=1.51\, V$
$\, \, \, \, \, E^\circ _{Cr_2 O ^{2-}_7/Cr^{3+}} =-1.33\, V;E^\circ_{Cl/Cl^-}=1.36\, V$
Based on the data given above strongest oxidising agent will be
- $Cl$
- $Cr^{3+}$
- $Mn^{2+}$
- $MnO^-_4$
The Correct Option is D
Solution and Explanation
Top Questions on Redox reactions
- Consider the following redox reaction:\[\text{MnO}_4^- + \text{H}^+ + \text{H}_2 \text{C}_2 \text{O}_4 \rightleftharpoons \text{Mn}^{2+} + \text{H}_2 \text{O} + \text{CO}_2\]The standard reduction potentials are given as below (E\(_\text{red}\)):\[E^\circ_{\text{MnO}_4^-/\text{Mn}^{2+}} = +1.51 \, \text{V}\]\[E^\circ_{\text{CO}_2/\text{H}_2 \text{C}_2 \text{O}_4} = -0.49 \, \text{V}\]If the equilibrium constant of the above reaction is given as \(K_\text{eq} = 10^x\), then the value of (x = ________ ) (nearest integer).
- JEE Main - 2024
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- Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): In aqueous solutions \( \text{Cr}^{2+} \) is reducing while \( \text{Mn}^{3+} \) is oxidising in nature.
Reason (R): Extra stability to half-filled electronic configuration is observed than incompletely filled electronic configuration.
In the light of the above statement, choose the most appropriate answer from the options given below:- JEE Main - 2024
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- The number of ions from the following that have the ability to liberate hydrogen from a dilute acid is _______. Ti2+, Cr2+ and V2+.
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- Only \( 2 \, \text{mL} \) of \( \text{KMnO}_4 \) solution of unknown molarity is required to reach the end point of a titration of \( 20 \, \text{mL} \) of oxalic acid (\( 2 \, \text{M} \)) in acidic medium. The molarity of \( \text{KMnO}_4 \) solution should be ______ \( \text{M} \).
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- When \( \text{MnO}_2 \) and \( \text{H}_2\text{SO}_4 \) is added to a salt (A), the greenish yellow gas liberated as salt (A) is:
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Questions Asked in JEE Main exam
- Let \[\vec{a} = \hat{i} + \hat{j} + \hat{k}, \quad \vec{b} = -\hat{i} - 8\hat{j} + 2\hat{k}, \quad \text{and} \quad \vec{c} = 4\hat{i} + c_2\hat{j} + c_3\hat{k} \]be three vectors such that \[\vec{b} \times \vec{a} = \vec{c} \times \vec{a}.\]If the angle between the vector $\vec{c}$ and the vector $3\hat{i} + 4\hat{j} + \hat{k}$ is $\theta$, then the greatest integer less than or equal to $\tan^2 \theta$ is:
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- 10 mL of gaseous hydrocarbon on combustion gives 40 mL of CO\(_2\)(g) and 50 mL of water vapour. The total number of carbon and hydrogen atoms in the hydrocarbon is ______ .
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- If each term of a geometric progression \( a_1, a_2, a_3, \dots \) with \( a_1 = \frac{1}{8} \) and \( a_2 \neq a_1 \), is the arithmetic mean of the next two terms and \( S_n = a_1 + a_2 + \dots + a_n \), then \( S_{20} - S_{18} \) is equal to
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A body of mass 1000 kg is moving horizontally with a velocity of 6 m/s. If 200 kg extra mass is added, the final velocity (in m/s) is:
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- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
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Concepts Used:
Redox Reactions
Redox Reaction:
Redox reactions are chemical reactions where oxidation and reduction take place simultaneously. In this type of reaction, there is a gain of electrons for one chemical species while the other loses electrons or simply involves transfer of electrons. The species that loses electrons is oxidized while the one that gains electrons is reduced.
Types of Redox Reactions:
Redox reactions can be differentiated into 4 categories namely combination reactions, decomposition reactions, displacement reactions, and disproportionation reactions. Each is explained separately below:
Combination Reaction:
In this, the molecules combine to form new compounds. For example, when magnesium reacts to nitrogen.
Decomposition Reaction:
Opposite to the combination reaction, here there is a breakdown of compounds to simpler substances. For example, electrolysis of water.
Displacement Reaction:
In this, the more reactive metal will displace the less reactive one in a chemical reaction. The reactivity of an element is represented in a series called the reactivity series (arranged in decreasing order of reactivity) which makes it easier to determine the chemical reaction and its products.
Disproportionation Reaction:
This is a peculiar type of reaction where an element showing a particular oxidation state will be oxidized and reduced simultaneously. Another thing to note is that these reactions will always have an element that can exhibit three oxidation states.
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