Question:

For $K_4[Fe(CN)_6]$, coordination number and oxidation state are respectively

Updated On: Jul 28, 2022
  • $6$, $6$
  • $2$, $2$
  • $6$, $2$
  • $2$, $6$
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The Correct Option is C

Solution and Explanation

In $K_4[Fe(CN )_6]$, the central metal $Fe$ is surrounded by $6\, CN ^-$ ligands. Hence, coordination no. of $Fe$ is $6$. Oxidation state of $Fe = 4 + x + (-6) = 0$ $\Rightarrow x - 2 = 0$ $\Rightarrow x = + 2$
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Concepts Used:

Coordination Compounds

A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.

Coordination entity:

A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.

Ligands:

A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.