Question:

First ionisation energy of alkali metals is very low but second ionisation energy is very high because

Updated On: Jul 6, 2022
  • alkali metals acquire noble gas configuration after losing one electron
  • a large amount of energy is required to remove electron from a cation
  • alkali metals can form only univalent ions
  • first group elements can lose only one electron
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The Correct Option is A

Solution and Explanation

All the alkali metals have one valence electron $n s^{1}$. outside the noble gas core. The loosely held s-electron in the outermost valence shell of these elements makes them the most electropositive metals. They readily lose electron to give monovalent $M ^{+}$ions. So, the first ionization energy of alkali metals is low. after the removal of one electron, i.e. formation of monovalent $M ^{+}$ ion, the metal atom attains noble gas configuration, so they require every high ionization energy to remove electron from stable noble gas configuration. Therefore the second ionization energy is very high as compared to first ionization energy.
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Concepts Used:

Group 1 Elements

Group one of alkali metals is s-block elements with just one electron in their s-orbital. They are are alkali metals. They are named so because of the alkaline nature of the hydroxides and oxides.

Alkali metals are characterized by one s-electron in the valence shell of their atoms.

Alkali metals have a corresponding [Noble gas] ns1 electronic configuration. They occupy the first column of the periodic table. Alkali elements are:

  • Lithium(Li)
  • Sodium(Na)
  • Potassium (K)
  • Rubidium (Ru)
  • Cesium (Cs)
  • Francium (Fr)

They have occupied successive periods from first to seven. Francium is a radioactive element with very low half-life.

Electronic Configuration:

  • Alkali metals have one electron in their valence shell.
  • The electronic configuration is given by ns1. For example, the electronic configuration of lithium is given by 1ns1 2ns1.
  • They tend to lose the outer shell electron to form cations with charge +1 (monovalent ions).

This makes them the most electropositive elements and due to the same reason, they are not found in the pure state.