Part (a): Energy Band Diagram of an N-Type Semiconductor at \( T > 0\,\text{K} \)
N-type semiconductors are doped with donor impurities (e.g., phosphorus in silicon), introducing donor levels \( E_d \) just below the conduction band edge \( E_c \). At \( T > 0 \, \text{K} \), electrons are thermally excited from \( E_d \) to the conduction band, making electrons the majority carriers.
Step 1: Key Features
Step 2: Diagram Description
Part (b): Energy Band Diagram of a P-Type Semiconductor at \( T > 0\,\text{K} \)
P-type semiconductors are doped with acceptor impurities (e.g., boron in silicon), introducing acceptor levels \( E_a \) just above the valence band edge \( E_v \). At \( T > 0 \, \text{K} \), electrons from the valence band occupy \( E_a \), creating holes in the valence band.
Step 1: Key Features
Step 2: Diagram Description
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]
Write chemical equations of the following reactions:
(i) Phenol is treated with conc. HNO\(_3\)
(ii) Propene is treated with B\(_2\)H\(_6\) followed by oxidation by H\(_2\)O\(_2\)/OH\(^-\)
(iii) Sodium t-butoxide is treated with CH\(_3\)Cl