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Dehydration of hydrates of halides of calcium, barium and strontium i.e., $CaCl_2 \cdot 6H_2O$, $BaCl_2 \cdot 2H_2O$, $SrCl_2 \cdot 6H_2O$, can be achieved by heating. These become wet on keeping in air. Which of the following statements is correct about these halides ?
Dehydration of hydrates of halides of calcium, barium and strontium i.e., $CaCl_2 \cdot 6H_2O$, $BaCl_2 \cdot 2H_2O$, $SrCl_2 \cdot 6H_2O$, can be achieved by heating. These become wet on keeping in air. Which of the following statements is correct about these halides ?
Updated On: Jul 6, 2022
- Act as dehydrating agent
- Can absorb moisture from air
- Tendency to form hydrate decreases from calcium to barium
- All of the above
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The Correct Option is D
Solution and Explanation
Halides of calcium, barium and strontium act as dehydrating agent as they are hygroscopic in nature. They absorb moisture. Also they have tendency to form hydrate which decreases from $Ca ^{2+}$ to $Sr ^{2+}$ due to increase in size and decrease in polarization power.
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Concepts Used:
Group 1 Elements
Group one of alkali metals is s-block elements with just one electron in their s-orbital. They are are alkali metals. They are named so because of the alkaline nature of the hydroxides and oxides.
Alkali metals are characterized by one s-electron in the valence shell of their atoms.
Alkali metals have a corresponding [Noble gas] ns1 electronic configuration. They occupy the first column of the periodic table. Alkali elements are:
- Lithium(Li)
- Sodium(Na)
- Potassium (K)
- Rubidium (Ru)
- Cesium (Cs)
- Francium (Fr)
They have occupied successive periods from first to seven. Francium is a radioactive element with very low half-life.
Electronic Configuration:
- Alkali metals have one electron in their valence shell.
- The electronic configuration is given by ns1. For example, the electronic configuration of lithium is given by 1ns1 2ns1.
- They tend to lose the outer shell electron to form cations with charge +1 (monovalent ions).
This makes them the most electropositive elements and due to the same reason, they are not found in the pure state.
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