Concept:
When an \(\alpha\)-particle moves directly toward a positively charged nucleus, it experiences electrostatic repulsion.
At the closest distance of approach, the kinetic energy of the \(\alpha\)-particle becomes completely converted into electrostatic potential energy.
So, at minimum distance:
\[
\text{Kinetic energy}=\text{Electrostatic potential energy}
\]
The formula used is:
\[
E=\frac{1}{4\pi\varepsilon_0}\frac{Z_1Z_2e^2}{r}
\]
In nuclear physics, a useful shortcut is:
\[
r(\text{fm})=\frac{1.44Z_1Z_2}{E(\text{MeV})}
\]
Step 1: Write the given values.
For an \(\alpha\)-particle:
\[
Z_1=2
\]
For lead nucleus:
\[
Z_2=82
\]
Energy of \(\alpha\)-particle:
\[
E=400\ \text{keV}
\]
Convert keV into MeV:
\[
400\ \text{keV}=0.4\ \text{MeV}
\]
Step 2: Apply the closest approach formula.
\[
r=\frac{1.44Z_1Z_2}{E}
\]
Substitute values:
\[
r=\frac{1.44\times2\times82}{0.4}
\]
Step 3: Calculate the value.
First multiply the numerator:
\[
1.44\times2=2.88
\]
\[
2.88\times82=236.16
\]
Now divide by \(0.4\):
\[
r=\frac{236.16}{0.4}=590.4\ \text{fm}
\]
So:
\[
r\approx590\ \text{fm}
\]
Step 4: Convert femtometer into picometer.
We know:
\[
1\ \text{pm}=1000\ \text{fm}
\]
Therefore:
\[
590\ \text{fm}=0.590\ \text{pm}
\]
\[
r\approx0.59\ \text{pm}
\]
Step 5: Check the options.
Option (A) \(0.59\ \text{nm}\) is too large.
Option (B) \(0.59\ \text{\AA}\) is also much larger than the calculated value.
Option (C) \(5.9\ \text{pm}\) is 10 times larger than the correct value.
Option (D) \(0.59\ \text{pm}\) matches the calculated result.
Hence, the correct answer is:
\[
\boxed{(D)\ 0.59\ \text{pm}}
\]