Question:

A solution of a compound $X$ in dilute $HCl$ on treatment with a solution of $BaCl_2$ gives a white precipitate of a compound $Y$ which is insoluble in cone. $HNO_3$ and conc. $HCl$. Compound $X$ imparts golden yellow colour to the flame. $\underset{\text{(imparts golden yellow colour)}}{ {X (Solution \,in \,dilute HCl) }}$ $+\, {BaCl2 -> }$$\underset{\text{Whit ppt}}{ {Y}}$ $ {->[\text{Conc}. HNO_3][\text{Conc}.HCl] Insoluble}$ What are compounds $X$ and $Y$ ?

Updated On: Jul 6, 2022
  • $X$ is $MgCl_2$ and $Y$ is $BaSO_4$
  • $X$ is $CaCl_2$ and $Y$ is $BaSO_4$
  • $X$ is $Na_2SO_4$ and $Y$ is $BaSO_4$
  • $X$ is $MgSO_4$ and $Y$ is $BaSO_4$
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The Correct Option is C

Solution and Explanation

$\underset{\text{(X)}}{ {Na2SO4}} {+BaCl2 \to}$ $\underset{\text{(Y)}}{ {BaSO4}} {+2NaCl}$
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Concepts Used:

Group 1 Elements

Group one of alkali metals is s-block elements with just one electron in their s-orbital. They are are alkali metals. They are named so because of the alkaline nature of the hydroxides and oxides.

Alkali metals are characterized by one s-electron in the valence shell of their atoms.

Alkali metals have a corresponding [Noble gas] ns1 electronic configuration. They occupy the first column of the periodic table. Alkali elements are:

  • Lithium(Li)
  • Sodium(Na)
  • Potassium (K)
  • Rubidium (Ru)
  • Cesium (Cs)
  • Francium (Fr)

They have occupied successive periods from first to seven. Francium is a radioactive element with very low half-life.

Electronic Configuration:

  • Alkali metals have one electron in their valence shell.
  • The electronic configuration is given by ns1. For example, the electronic configuration of lithium is given by 1ns1 2ns1.
  • They tend to lose the outer shell electron to form cations with charge +1 (monovalent ions).

This makes them the most electropositive elements and due to the same reason, they are not found in the pure state.