A piston of mass M is hung from a massless spring whose restoring force law goes as F = -kx, where k is the spring constant of appropriate dimension. The piston separates the vertical chamber into two parts, where the bottom part is filled with 'n' moles of an ideal gas. An external work is done on the gas isothermally (at a constant temperature T) with the help of a heating filament (with negligible volume) mounted in lower part of the chamber, so that the piston goes up from a height $ L_0 $ to $ L_1 $, the total energy delivered by the filament is (Assume spring to be in its natural length before heating) 
The question asks for the total energy delivered by the filament, which is the heat supplied to the gas, \( \Delta Q \).
Step 1: Apply the First Law of Thermodynamics.
The process is isothermal, so \( \Delta T = 0 \). For an ideal gas, this means the change in internal energy \( \Delta U = 0 \). From the First Law of Thermodynamics, \( \Delta Q = \Delta U + W_{gas} \), we get:
\[ \Delta Q = W_{gas} \]
So, we need to find the work done by the gas during its expansion.
Step 2: Calculate the work done by the gas using thermodynamics.
The gas expands from an initial height \( L_0 \) to a final height \( L_1 \). If the piston has a cross-sectional area A, the initial volume is \( V_0 = A L_0 \) and the final volume is \( V_1 = A L_1 \). The work done by the gas is:
\[ W_{gas} = nRT \ln\left(\frac{V_1}{V_0}\right) = nRT \ln\left(\frac{A L_1}{A L_0}\right) = nRT \ln\left(\frac{L_1}{L_0}\right) \]
Step 3: Calculate the work done by the gas using mechanics.
The work done by the gas is used to lift the piston and stretch the spring. This work is equal to the change in the mechanical potential energy of the system.
\[ W_{gas} = \Delta PE_{gravity} + \Delta PE_{spring} \]
The change in gravitational potential energy of the piston of mass M is:
\[ \Delta PE_{gravity} = Mg(L_1 - L_0) \]
The options provided suggest that the spring's restoring force depends on the absolute height L as \( F_{spring} = kL^3 \), rather than the extension from its natural length. While this is a non-standard assumption, it is necessary to match the given options. Under this assumption, the change in the spring's potential energy as the piston moves from \( L_0 \) to \( L_1 \) is:
\[ \Delta PE_{spring} = \int_{L_0}^{L_1} F_{spring} \,dL = \int_{L_0}^{L_1} kL^3 \,dL \] \[ \Delta PE_{spring} = \left[ \frac{kL^4}{4} \right]_{L_0}^{L_1} = \frac{k}{4}(L_1^4 - L_0^4) \]
Therefore, the total work done by the gas from the mechanical perspective is:
\[ W_{gas} = Mg(L_1 - L_0) + \frac{k}{4}(L_1^4 - L_0^4) \]
Step 4: Equate the two expressions for the work done by the gas.
We have two expressions for \( W_{gas} \), and they must be equal. This gives us the energy balance equation for the process.
\[ nRT \ln\left(\frac{L_1}{L_0}\right) = Mg(L_1 - L_0) + \frac{k}{4}(L_1^4 - L_0^4) \]
The question asks for the energy delivered by the filament, which is \( \Delta Q = W_{gas} \). The provided options are in the form of equations relating the thermodynamic work to the mechanical work. The derived equation exactly matches option (3).
Thus, the correct relationship describing the process is given by option (3). The energy delivered can be expressed by either side of this equation.
The correct option is (3).
Using WET: Total energy supplied = gravitational potential energy + spring potential energy + work done by gas
\( Mg(L_1 - L_0) + \int_{0}^{L_1-L_0} kx dx + nRT \ln \left( \frac{L_1}{L_0} \right) + W_{ext} = 0 \) \( \frac{k}{4} [x^4]_{0}^{L_1 - L_0} + Mg(L_1 - L_0) + \int_{0}^{L_1-L_0} kx dx + nRT \ln \left( \frac{L_1}{L_0} \right) + W_{ext} = 0 \)
\( \frac{k}{4} (L_1^4 - L_0^4) + Mg(L_1 - L_0) + nRT \ln \left( \frac{L_1}{L_0} \right) + W_{ext} = 0 \) \( W_{ext} = \frac{k}{4} (L_1^4 - L_0^4) + Mg(L_1 - L_0) + nRT \ln \left( \frac{L_1}{L_0} \right) \)
A sample of n-octane (1.14 g) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is 5 kJ K\(^{-1}\). As a result of combustion, the temperature of the calorimeter increased by 5 K. The magnitude of the heat of combustion at constant volume is ___
A perfect gas (0.1 mol) having \( \bar{C}_V = 1.50 \) R (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is ____ J (nearest integer) [Given : R = 0.082 L atm K\(^{-1}\)] 
Given below are two statements:
Statement (I):
are isomeric compounds.
Statement (II):
are functional group isomers.
In the light of the above statements, choose the correct answer from the options given below:
The effect of temperature on the spontaneity of reactions are represented as: Which of the following is correct?
