
In thermodynamics, the first law states that the change in internal energy of a system, ΔU, is equal to the heat added to the system, Q, minus the work done by the system, W. Mathematically, this is expressed as ΔU = Q - W.
We analyze the given processes as follows:
For process 1-2:
Heat absorbed, Q1-2 = 150 kJ
Work done by the system, W1-2 = 90 kJ
Change in internal energy, ΔU1-2 = Q1-2 - W1-2 = 150 kJ - 90 kJ = 60 kJ
For process 2-3:
Work done on the system, W2-3 = -80 kJ (since work is done on the system, it's negative)
Heat rejected, Q2-3 = -60 kJ (as it's rejected, it's negative)
Change in internal energy, ΔU2-3 = Q2-3 - W2-3 = -60 kJ - (-80 kJ) = 20 kJ
Total change from state 1 to state 3:
ΔU1-3 = ΔU1-2 + ΔU2-3 = 60 kJ + 20 kJ = 80 kJ
For an adiabatic process (no heat exchange, Q = 0) from state 3 back to state 1:
ΔU3-1 = Q3-1 - W3-1 = 0 - W3-1
Since the total change in internal energy around the full cycle must be zero, ΔU1-3 + ΔU3-1 = 0, it follows that:
80 kJ - W3-1 = 0
W3-1 = 80 kJ
Thus, the work interaction needed to restore the system to the initial state by an adiabatic path is 80 kJ.
An ideal gas has undergone through the cyclic process as shown in the figure. Work done by the gas in the entire cycle is _____ $ \times 10^{-1} $ J. (Take $ \pi = 3.14 $) 
Match the List-I with List-II.
Choose the correct answer from the options given below:
The internal energy of air in $ 4 \, \text{m} \times 4 \, \text{m} \times 3 \, \text{m} $ sized room at 1 atmospheric pressure will be $ \times 10^6 \, \text{J} $. (Consider air as a diatomic molecule)
Two vessels A and B are connected via stopcock. Vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true? 
$\gamma_A$ is the specific heat ratio of monoatomic gas A having 3 translational degrees of freedom. $\gamma_B$ is the specific heat ratio of polyatomic gas B having 3 translational, 3 rotational degrees of freedom and 1 vibrational mode. If \[ \frac{\gamma_A}{\gamma_B} = \left( 1 + \frac{1}{n} \right) \] then the value of \( n \) is ___.
An electricity utility company charges ₹7 per kWh. If a 40-watt desk light is left on for 10 hours each night for 180 days, what would be the cost of energy consumption? If the desk light is on for 2 more hours each night for the 180 days, what would be the percentage-increase in the cost of energy consumption?
 
